Research output: Contribution to journal › Article › peer-review
Crystal structure and thermal behavior of KBr3O5. / Bubnova, R. S.; Fundamenskij, V. S.; Filatov, S. K.; Polyakova, I. G.
In: Doklady Akademii Nauk, Vol. 398, No. 5, 01.12.2004, p. 643-647.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Crystal structure and thermal behavior of KBr3O5
AU - Bubnova, R. S.
AU - Fundamenskij, V. S.
AU - Filatov, S. K.
AU - Polyakova, I. G.
PY - 2004/12/1
Y1 - 2004/12/1
N2 - The crystal structure solution results (based on X-ray diffraction data) are presented for the last unknown structure in the series of alkaline metal triborates. The phase KBr3O5 was crystallized from the melt (≈800°C) in a metastable state using glass as precursor. The compound belongs to the new structural type, structure anion represents a single boron-oxygen skeleton formed from three independent rigid triborate rings [B3O5]- consisting of two triangles BO3 and one tetrahedron BO4 characteristic for triborates. According to crystal-optic analysis, KBr3O5 crystals are biaxial, optically negative.
AB - The crystal structure solution results (based on X-ray diffraction data) are presented for the last unknown structure in the series of alkaline metal triborates. The phase KBr3O5 was crystallized from the melt (≈800°C) in a metastable state using glass as precursor. The compound belongs to the new structural type, structure anion represents a single boron-oxygen skeleton formed from three independent rigid triborate rings [B3O5]- consisting of two triangles BO3 and one tetrahedron BO4 characteristic for triborates. According to crystal-optic analysis, KBr3O5 crystals are biaxial, optically negative.
UR - http://www.scopus.com/inward/record.url?scp=12244291953&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:12244291953
VL - 398
SP - 643
EP - 647
JO - ДОКЛАДЫ АКАДЕМИИ НАУК
JF - ДОКЛАДЫ АКАДЕМИИ НАУК
SN - 0869-5652
IS - 5
ER -
ID: 53959603