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Crystal chemistry of selenates with mineral-like structures : VIII. Butlerite chains in the structure of K(UO2)(SeO4)(OH)(H2O). / Gurzhii, V. V.; Bessonov, A. A.; Krivovichev, S. V.; Tananaev, I. G.; Armbruster, T.; Myasoedov, B. F.

In: Geology of Ore Deposits, Vol. 51, No. 8, 2009, p. 833-837.

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Gurzhii, V. V. ; Bessonov, A. A. ; Krivovichev, S. V. ; Tananaev, I. G. ; Armbruster, T. ; Myasoedov, B. F. / Crystal chemistry of selenates with mineral-like structures : VIII. Butlerite chains in the structure of K(UO2)(SeO4)(OH)(H2O). In: Geology of Ore Deposits. 2009 ; Vol. 51, No. 8. pp. 833-837.

BibTeX

@article{e4ede4a6433f418e9dbee3af87661fc4,
title = "Crystal chemistry of selenates with mineral-like structures: VIII. Butlerite chains in the structure of K(UO2)(SeO4)(OH)(H2O)",
abstract = "A new potassium uranyl selenate compound K(UO2)(SeO4)(OH)(H2O) has been synthesized for the first time using the technique of evaporation from water solution. Its crystal structure has been solved by direct methods (monoclinic, P21/c,a = 8.0413(9) {\AA}, b = 8.0362(9) {\AA}, c = 11.6032(14) {\AA}, β = 106.925(2)°, V = 717.34(14) {\AA}3) and refined to R1 = 0.0319 (wR2 = 0.0824) for 1285 reflections with {pipe}F0{pipe} > 4σF. The structure consists of [(UO2(SeO4)(OH)(H2O)]- chains extending along axis b. In the chains, the uranyl pentagonal bipyramids are linked via bridged hydroxyl anions and tetrahedral oxoanions [SeO4]2-. Potassium ions are situated between these chains. No chains of that type have been observed in uranyl compounds earlier, but they had been detected in the structures of butlerite, parabutlerite, uklonskovite, fibroferrite, and a number of synthetic compounds.",
author = "Gurzhii, {V. V.} and Bessonov, {A. A.} and Krivovichev, {S. V.} and Tananaev, {I. G.} and T. Armbruster and Myasoedov, {B. F.}",
year = "2009",
doi = "10.1134/S1075701509080170",
language = "English",
volume = "51",
pages = "833--837",
journal = "Geology of Ore Deposits",
issn = "1075-7015",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "8",

}

RIS

TY - JOUR

T1 - Crystal chemistry of selenates with mineral-like structures

T2 - VIII. Butlerite chains in the structure of K(UO2)(SeO4)(OH)(H2O)

AU - Gurzhii, V. V.

AU - Bessonov, A. A.

AU - Krivovichev, S. V.

AU - Tananaev, I. G.

AU - Armbruster, T.

AU - Myasoedov, B. F.

PY - 2009

Y1 - 2009

N2 - A new potassium uranyl selenate compound K(UO2)(SeO4)(OH)(H2O) has been synthesized for the first time using the technique of evaporation from water solution. Its crystal structure has been solved by direct methods (monoclinic, P21/c,a = 8.0413(9) Å, b = 8.0362(9) Å, c = 11.6032(14) Å, β = 106.925(2)°, V = 717.34(14) Å3) and refined to R1 = 0.0319 (wR2 = 0.0824) for 1285 reflections with {pipe}F0{pipe} > 4σF. The structure consists of [(UO2(SeO4)(OH)(H2O)]- chains extending along axis b. In the chains, the uranyl pentagonal bipyramids are linked via bridged hydroxyl anions and tetrahedral oxoanions [SeO4]2-. Potassium ions are situated between these chains. No chains of that type have been observed in uranyl compounds earlier, but they had been detected in the structures of butlerite, parabutlerite, uklonskovite, fibroferrite, and a number of synthetic compounds.

AB - A new potassium uranyl selenate compound K(UO2)(SeO4)(OH)(H2O) has been synthesized for the first time using the technique of evaporation from water solution. Its crystal structure has been solved by direct methods (monoclinic, P21/c,a = 8.0413(9) Å, b = 8.0362(9) Å, c = 11.6032(14) Å, β = 106.925(2)°, V = 717.34(14) Å3) and refined to R1 = 0.0319 (wR2 = 0.0824) for 1285 reflections with {pipe}F0{pipe} > 4σF. The structure consists of [(UO2(SeO4)(OH)(H2O)]- chains extending along axis b. In the chains, the uranyl pentagonal bipyramids are linked via bridged hydroxyl anions and tetrahedral oxoanions [SeO4]2-. Potassium ions are situated between these chains. No chains of that type have been observed in uranyl compounds earlier, but they had been detected in the structures of butlerite, parabutlerite, uklonskovite, fibroferrite, and a number of synthetic compounds.

UR - http://www.scopus.com/inward/record.url?scp=77949695438&partnerID=8YFLogxK

U2 - 10.1134/S1075701509080170

DO - 10.1134/S1075701509080170

M3 - Article

AN - SCOPUS:77949695438

VL - 51

SP - 833

EP - 837

JO - Geology of Ore Deposits

JF - Geology of Ore Deposits

SN - 1075-7015

IS - 8

ER -

ID: 9152203