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Crystal chemistry and Raman spectroscopy of two synthetic sodalite-type aluminosilicates with [MoO4]2− and [WO4]2− groups. / Shchipalkina, Nadezhda V.; Zubkova, Natalia N.; Kotelnikov, Alexey R.; Koshlyakova, Natalia N.; Pekov, Igor V.; Ksenofontov, Dmitry A.; Britvin, Sergey N.

In: Physics and Chemistry of Minerals, Vol. 48, No. 5, 19, 05.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Shchipalkina, NV, Zubkova, NN, Kotelnikov, AR, Koshlyakova, NN, Pekov, IV, Ksenofontov, DA & Britvin, SN 2021, 'Crystal chemistry and Raman spectroscopy of two synthetic sodalite-type aluminosilicates with [MoO4]2− and [WO4]2− groups', Physics and Chemistry of Minerals, vol. 48, no. 5, 19. https://doi.org/10.1007/s00269-021-01144-8

APA

Shchipalkina, N. V., Zubkova, N. N., Kotelnikov, A. R., Koshlyakova, N. N., Pekov, I. V., Ksenofontov, D. A., & Britvin, S. N. (2021). Crystal chemistry and Raman spectroscopy of two synthetic sodalite-type aluminosilicates with [MoO4]2− and [WO4]2− groups. Physics and Chemistry of Minerals, 48(5), [19]. https://doi.org/10.1007/s00269-021-01144-8

Vancouver

Shchipalkina NV, Zubkova NN, Kotelnikov AR, Koshlyakova NN, Pekov IV, Ksenofontov DA et al. Crystal chemistry and Raman spectroscopy of two synthetic sodalite-type aluminosilicates with [MoO4]2− and [WO4]2− groups. Physics and Chemistry of Minerals. 2021 May;48(5). 19. https://doi.org/10.1007/s00269-021-01144-8

Author

Shchipalkina, Nadezhda V. ; Zubkova, Natalia N. ; Kotelnikov, Alexey R. ; Koshlyakova, Natalia N. ; Pekov, Igor V. ; Ksenofontov, Dmitry A. ; Britvin, Sergey N. / Crystal chemistry and Raman spectroscopy of two synthetic sodalite-type aluminosilicates with [MoO4]2− and [WO4]2− groups. In: Physics and Chemistry of Minerals. 2021 ; Vol. 48, No. 5.

BibTeX

@article{bc27b4cf134e4ac6961d43fbf3978040,
title = "Crystal chemistry and Raman spectroscopy of two synthetic sodalite-type aluminosilicates with [MoO4]2− and [WO4]2− groups",
abstract = "The synthetic nosean- and ha{\"u}yne-like aluminosilicates with (MoO4)2− and (WO4)2− extra-framework anions were synthesized in H2O-bearing systems (3 kbar, 750 °C) and studied by means of electron microprobe analysis, Raman spectroscopy, powder and single-crystal X-ray diffraction. The nosean-like phase contains up to 10.6 wt% MoO3 and up to 5.1 wt% WO3; the maximum content of MoO3 in the ha{\"u}yne-like phase is 22.5 wt%. The nosean-like phase with (MoO4)2− and (WO4)2− is cubic, P-43m, a = 9.1278(10) {\AA}, V = 760.498(14) {\AA}3, Z = 1. This compound with the crystal chemical formula Na7.68[(Al,Si)12O24] {[(Mo0.65W0.35)O4]0.78□0.22}·H2O has a disordered Al/Si framework, that is caused by the high temperature of crystallization (t = 750 °C) with further quenching at room temperature. Despite the same conditions of synthesis, the ha{\"u}yne-like phase with (MoO4)2−, Na5.12Ca1.92[Al6Si6O24](MoO4)1.52 has an Al/Si-ordered framework. Its space group is P-43n, a = 9.1516(4) {\AA}, V = 766.46(6) {\AA}3, Z = 1. In both synthesized sodalite-type aluminosilicates the anion groups (MoO4)2− and (WO4)2− are dynamically disordered. The polarized Raman spectra of both aluminosilicates show that Raman-active modes of (MoO4)2− and (WO4)2− correspond to vibrations of tetrahedral anions with symmetry Td. The presence of H2O was fixed only in the nosean-like compound and no preferred orientation of water molecule was detected.",
keywords = "Aluminosilicates, Crystal chemistry, Ha{\"u}yne, Raman spectroscopy, Sodalite, Synthesis, yne, Ha&#252",
author = "Shchipalkina, {Nadezhda V.} and Zubkova, {Natalia N.} and Kotelnikov, {Alexey R.} and Koshlyakova, {Natalia N.} and Pekov, {Igor V.} and Ksenofontov, {Dmitry A.} and Britvin, {Sergey N.}",
note = "Publisher Copyright: {\textcopyright} 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = may,
doi = "10.1007/s00269-021-01144-8",
language = "English",
volume = "48",
journal = "Physics and Chemistry of Minerals",
issn = "0342-1791",
publisher = "Springer Nature",
number = "5",

}

RIS

TY - JOUR

T1 - Crystal chemistry and Raman spectroscopy of two synthetic sodalite-type aluminosilicates with [MoO4]2− and [WO4]2− groups

AU - Shchipalkina, Nadezhda V.

AU - Zubkova, Natalia N.

AU - Kotelnikov, Alexey R.

AU - Koshlyakova, Natalia N.

AU - Pekov, Igor V.

AU - Ksenofontov, Dmitry A.

AU - Britvin, Sergey N.

N1 - Publisher Copyright: © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/5

Y1 - 2021/5

N2 - The synthetic nosean- and haüyne-like aluminosilicates with (MoO4)2− and (WO4)2− extra-framework anions were synthesized in H2O-bearing systems (3 kbar, 750 °C) and studied by means of electron microprobe analysis, Raman spectroscopy, powder and single-crystal X-ray diffraction. The nosean-like phase contains up to 10.6 wt% MoO3 and up to 5.1 wt% WO3; the maximum content of MoO3 in the haüyne-like phase is 22.5 wt%. The nosean-like phase with (MoO4)2− and (WO4)2− is cubic, P-43m, a = 9.1278(10) Å, V = 760.498(14) Å3, Z = 1. This compound with the crystal chemical formula Na7.68[(Al,Si)12O24] {[(Mo0.65W0.35)O4]0.78□0.22}·H2O has a disordered Al/Si framework, that is caused by the high temperature of crystallization (t = 750 °C) with further quenching at room temperature. Despite the same conditions of synthesis, the haüyne-like phase with (MoO4)2−, Na5.12Ca1.92[Al6Si6O24](MoO4)1.52 has an Al/Si-ordered framework. Its space group is P-43n, a = 9.1516(4) Å, V = 766.46(6) Å3, Z = 1. In both synthesized sodalite-type aluminosilicates the anion groups (MoO4)2− and (WO4)2− are dynamically disordered. The polarized Raman spectra of both aluminosilicates show that Raman-active modes of (MoO4)2− and (WO4)2− correspond to vibrations of tetrahedral anions with symmetry Td. The presence of H2O was fixed only in the nosean-like compound and no preferred orientation of water molecule was detected.

AB - The synthetic nosean- and haüyne-like aluminosilicates with (MoO4)2− and (WO4)2− extra-framework anions were synthesized in H2O-bearing systems (3 kbar, 750 °C) and studied by means of electron microprobe analysis, Raman spectroscopy, powder and single-crystal X-ray diffraction. The nosean-like phase contains up to 10.6 wt% MoO3 and up to 5.1 wt% WO3; the maximum content of MoO3 in the haüyne-like phase is 22.5 wt%. The nosean-like phase with (MoO4)2− and (WO4)2− is cubic, P-43m, a = 9.1278(10) Å, V = 760.498(14) Å3, Z = 1. This compound with the crystal chemical formula Na7.68[(Al,Si)12O24] {[(Mo0.65W0.35)O4]0.78□0.22}·H2O has a disordered Al/Si framework, that is caused by the high temperature of crystallization (t = 750 °C) with further quenching at room temperature. Despite the same conditions of synthesis, the haüyne-like phase with (MoO4)2−, Na5.12Ca1.92[Al6Si6O24](MoO4)1.52 has an Al/Si-ordered framework. Its space group is P-43n, a = 9.1516(4) Å, V = 766.46(6) Å3, Z = 1. In both synthesized sodalite-type aluminosilicates the anion groups (MoO4)2− and (WO4)2− are dynamically disordered. The polarized Raman spectra of both aluminosilicates show that Raman-active modes of (MoO4)2− and (WO4)2− correspond to vibrations of tetrahedral anions with symmetry Td. The presence of H2O was fixed only in the nosean-like compound and no preferred orientation of water molecule was detected.

KW - Aluminosilicates

KW - Crystal chemistry

KW - Haüyne

KW - Raman spectroscopy

KW - Sodalite

KW - Synthesis

KW - yne

KW - Ha&#252

UR - http://www.scopus.com/inward/record.url?scp=85104158474&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/b846fdaa-c292-3ed7-9c13-ab00dcaffc5a/

U2 - 10.1007/s00269-021-01144-8

DO - 10.1007/s00269-021-01144-8

M3 - Article

AN - SCOPUS:85104158474

VL - 48

JO - Physics and Chemistry of Minerals

JF - Physics and Chemistry of Minerals

SN - 0342-1791

IS - 5

M1 - 19

ER -

ID: 76725287