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Critical Effect of the Length of Counterions in Mesogenic Lanthanide Complexes on the Electro-Optical Properties of Their Melts. / Polushin, S. G.; Lezova, I. E.; Polushina, G. E.; Rogozhin, V. B.; Ryumtsev, E. I.; Romanova, K. A.; Galyametdinov, Yu G.

In: JETP Letters, Vol. 107, No. 7, 01.04.2018, p. 431-434.

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@article{6f0d203437fb4c92a8d7ce6304baebf2,
title = "Critical Effect of the Length of Counterions in Mesogenic Lanthanide Complexes on the Electro-Optical Properties of Their Melts",
abstract = "Isotropic melts of nine metallomesogenic complexes with a smectic-А phase have been studied by the electric birefringence method. Complexes include Dy, Tb, Gd, and Er rare-earth ions, Schiff bases as ligands, and alkyl sulfate or nitric-acid counterions. It has been shown for the first time that both the magnitude and the sign of the electro-optical effect in the isotropic phase for the studied substances are determined by the length of counterions. This means that the dielectric anisotropy of smectic lanthanide complexes can vary widely depending on counterions: it can be positive, negative, or close to zero.",
keywords = "Isotropic melts, metallomesogenic complexes, electro-optical effect",
author = "Polushin, {S. G.} and Lezova, {I. E.} and Polushina, {G. E.} and Rogozhin, {V. B.} and Ryumtsev, {E. I.} and Romanova, {K. A.} and Galyametdinov, {Yu G.}",
year = "2018",
month = apr,
day = "1",
doi = "10.1134/S0021364018070068",
language = "English",
volume = "107",
pages = "431--434",
journal = "JETP Letters",
issn = "0021-3640",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "7",

}

RIS

TY - JOUR

T1 - Critical Effect of the Length of Counterions in Mesogenic Lanthanide Complexes on the Electro-Optical Properties of Their Melts

AU - Polushin, S. G.

AU - Lezova, I. E.

AU - Polushina, G. E.

AU - Rogozhin, V. B.

AU - Ryumtsev, E. I.

AU - Romanova, K. A.

AU - Galyametdinov, Yu G.

PY - 2018/4/1

Y1 - 2018/4/1

N2 - Isotropic melts of nine metallomesogenic complexes with a smectic-А phase have been studied by the electric birefringence method. Complexes include Dy, Tb, Gd, and Er rare-earth ions, Schiff bases as ligands, and alkyl sulfate or nitric-acid counterions. It has been shown for the first time that both the magnitude and the sign of the electro-optical effect in the isotropic phase for the studied substances are determined by the length of counterions. This means that the dielectric anisotropy of smectic lanthanide complexes can vary widely depending on counterions: it can be positive, negative, or close to zero.

AB - Isotropic melts of nine metallomesogenic complexes with a smectic-А phase have been studied by the electric birefringence method. Complexes include Dy, Tb, Gd, and Er rare-earth ions, Schiff bases as ligands, and alkyl sulfate or nitric-acid counterions. It has been shown for the first time that both the magnitude and the sign of the electro-optical effect in the isotropic phase for the studied substances are determined by the length of counterions. This means that the dielectric anisotropy of smectic lanthanide complexes can vary widely depending on counterions: it can be positive, negative, or close to zero.

KW - Isotropic melts, metallomesogenic complexes, electro-optical effect

UR - http://www.scopus.com/inward/record.url?scp=85048196994&partnerID=8YFLogxK

U2 - 10.1134/S0021364018070068

DO - 10.1134/S0021364018070068

M3 - Article

AN - SCOPUS:85048196994

VL - 107

SP - 431

EP - 434

JO - JETP Letters

JF - JETP Letters

SN - 0021-3640

IS - 7

ER -

ID: 47945065