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Coupling of platinated triguanides with platinum-activated nitriles as a novel strategy for generation of dimetallic systems. / Serebryanskaya, T.V.; Novikov, A.S.; Gushchin, P.V.; Zolotarev, A.A.; Gurzhiy, V.V.; Kukushkin, V.Y.

In: Dalton Transactions, Vol. 44, No. 13, 2015, p. 6003-6011.

Research output: Contribution to journal › Article › peer-review

Harvard

Serebryanskaya, TV, Novikov, AS, Gushchin, PV, Zolotarev, AA, Gurzhiy, VV & Kukushkin, VY 2015, 'Coupling of platinated triguanides with platinum-activated nitriles as a novel strategy for generation of dimetallic systems', Dalton Transactions, vol. 44, no. 13, pp. 6003-6011. https://doi.org/10.1039/c4dt03870c, https://doi.org/10.1039/c4dt03870c

APA

Serebryanskaya, T. V., Novikov, A. S., Gushchin, P. V., Zolotarev, A. A., Gurzhiy, V. V., & Kukushkin, V. Y. (2015). Coupling of platinated triguanides with platinum-activated nitriles as a novel strategy for generation of dimetallic systems. Dalton Transactions, 44(13), 6003-6011. https://doi.org/10.1039/c4dt03870c, https://doi.org/10.1039/c4dt03870c

Vancouver

Serebryanskaya TV, Novikov AS, Gushchin PV, Zolotarev AA, Gurzhiy VV, Kukushkin VY. Coupling of platinated triguanides with platinum-activated nitriles as a novel strategy for generation of dimetallic systems. Dalton Transactions. 2015;44(13):6003-6011. https://doi.org/10.1039/c4dt03870c, https://doi.org/10.1039/c4dt03870c

Author

Serebryanskaya, T.V. ; Novikov, A.S. ; Gushchin, P.V. ; Zolotarev, A.A. ; Gurzhiy, V.V. ; Kukushkin, V.Y. / Coupling of platinated triguanides with platinum-activated nitriles as a novel strategy for generation of dimetallic systems. In: Dalton Transactions. 2015 ; Vol. 44, No. 13. pp. 6003-6011.

BibTeX

@article{ca73b55617ea43a2999df22e0354c99f,
title = "Coupling of platinated triguanides with platinum-activated nitriles as a novel strategy for generation of dimetallic systems",
abstract = "One of two PtIV-activated propanenitriles in trans-[PtCl4(EtCN)2] is involved in platinum(IV)-mediated nitrile–imine coupling with the platinum(II)-based metallacycles [PtCl2{NHvC(NR2)N(Ph)C(vNH)N(Ph)- C(NR2)vNH}] [R2 = Me2 (1a), C5H10 (1b)] yielding diplatinum products, whose structures depend on molar ratios between the reactants. At a 1 : 1 ratio, the mixed-valence platinum(II)/platinum(IV) species [PtCl4{NHvC(NR2)N(Ph)C{v[(N(Et)CvNH)PtCl2(EtCN)]}N(Ph)C(NR2)vNH}] [R2 = Me2 (2a), (CH2)5 (2b)] were generated, whereas at a 1 : 2 ratio the dinuclear platinum(II)/platinum(II) complexes [PtCl2{NHv C(NR2)N(Ph)C{v[(N(Et)CvNH)PtCl2(EtCN)]}N(Ph)C(NR2)vNH}] [R2 = Me2 (3a), (CH2)5 (3b)] were obtained. In contrast to the nitrile–imine coupling observed for the platinum(IV) dinitrile complex, the reaction between the platinum(II) congener trans-[PtCl2(EtCN)2] and any one of 1a,b gives exclusively the substituted dimetallic platinum(II)/platinum(II) products [PtCl2{NHvC(NR2)N(Ph)C{v[(NH)PtCl2(EtCN)]}N(Ph)- C(NR2)vNH}] [R",
keywords = "Platinum(IV), platinum(II), coordinated nitrile, bimetallic complexes, coupling",
author = "T.V. Serebryanskaya and A.S. Novikov and P.V. Gushchin and A.A. Zolotarev and V.V. Gurzhiy and V.Y. Kukushkin",
note = "cited By 2",
year = "2015",
doi = "10.1039/c4dt03870c",
language = "English",
volume = "44",
pages = "6003--6011",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "13",

}

RIS

TY - JOUR

T1 - Coupling of platinated triguanides with platinum-activated nitriles as a novel strategy for generation of dimetallic systems

AU - Serebryanskaya, T.V.

AU - Novikov, A.S.

AU - Gushchin, P.V.

AU - Zolotarev, A.A.

AU - Gurzhiy, V.V.

AU - Kukushkin, V.Y.

N1 - cited By 2

PY - 2015

Y1 - 2015

N2 - One of two PtIV-activated propanenitriles in trans-[PtCl4(EtCN)2] is involved in platinum(IV)-mediated nitrile–imine coupling with the platinum(II)-based metallacycles [PtCl2{NHvC(NR2)N(Ph)C(vNH)N(Ph)- C(NR2)vNH}] [R2 = Me2 (1a), C5H10 (1b)] yielding diplatinum products, whose structures depend on molar ratios between the reactants. At a 1 : 1 ratio, the mixed-valence platinum(II)/platinum(IV) species [PtCl4{NHvC(NR2)N(Ph)C{v[(N(Et)CvNH)PtCl2(EtCN)]}N(Ph)C(NR2)vNH}] [R2 = Me2 (2a), (CH2)5 (2b)] were generated, whereas at a 1 : 2 ratio the dinuclear platinum(II)/platinum(II) complexes [PtCl2{NHv C(NR2)N(Ph)C{v[(N(Et)CvNH)PtCl2(EtCN)]}N(Ph)C(NR2)vNH}] [R2 = Me2 (3a), (CH2)5 (3b)] were obtained. In contrast to the nitrile–imine coupling observed for the platinum(IV) dinitrile complex, the reaction between the platinum(II) congener trans-[PtCl2(EtCN)2] and any one of 1a,b gives exclusively the substituted dimetallic platinum(II)/platinum(II) products [PtCl2{NHvC(NR2)N(Ph)C{v[(NH)PtCl2(EtCN)]}N(Ph)- C(NR2)vNH}] [R

AB - One of two PtIV-activated propanenitriles in trans-[PtCl4(EtCN)2] is involved in platinum(IV)-mediated nitrile–imine coupling with the platinum(II)-based metallacycles [PtCl2{NHvC(NR2)N(Ph)C(vNH)N(Ph)- C(NR2)vNH}] [R2 = Me2 (1a), C5H10 (1b)] yielding diplatinum products, whose structures depend on molar ratios between the reactants. At a 1 : 1 ratio, the mixed-valence platinum(II)/platinum(IV) species [PtCl4{NHvC(NR2)N(Ph)C{v[(N(Et)CvNH)PtCl2(EtCN)]}N(Ph)C(NR2)vNH}] [R2 = Me2 (2a), (CH2)5 (2b)] were generated, whereas at a 1 : 2 ratio the dinuclear platinum(II)/platinum(II) complexes [PtCl2{NHv C(NR2)N(Ph)C{v[(N(Et)CvNH)PtCl2(EtCN)]}N(Ph)C(NR2)vNH}] [R2 = Me2 (3a), (CH2)5 (3b)] were obtained. In contrast to the nitrile–imine coupling observed for the platinum(IV) dinitrile complex, the reaction between the platinum(II) congener trans-[PtCl2(EtCN)2] and any one of 1a,b gives exclusively the substituted dimetallic platinum(II)/platinum(II) products [PtCl2{NHvC(NR2)N(Ph)C{v[(NH)PtCl2(EtCN)]}N(Ph)- C(NR2)vNH}] [R

KW - Platinum(IV)

KW - platinum(II)

KW - coordinated nitrile

KW - bimetallic complexes

KW - coupling

U2 - 10.1039/c4dt03870c

DO - 10.1039/c4dt03870c

M3 - Article

VL - 44

SP - 6003

EP - 6011

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 13

ER -

ID: 3941206