Research output: Contribution to journal › Article › peer-review
The aim of the present study is to extend the multiconfiguration Dirac-Fock approach to include spin polarization in order to study magnetically ordered systems. Routines handling time-dependent ionization phenomena adapted to multilevel and multichannel autoionization processes have been developed and used to describe the giant resonance in the Gd3+ absorption spectrum. In our calculation of the complete energy structure of 4d94f8 configuration it is discovered that the majority of the oscillator strength associated with the 4d-4f transitions is limited to a relatively narrow spectral width, creating a giant resonance. Our calculations take account of the most important correlation effects, and the agreement with the experimentally observed giant resonance in gadolinium is quite good.
Original language | English |
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Pages (from-to) | 575-584 |
Number of pages | 10 |
Journal | International Journal of Quantum Chemistry |
Volume | 65 |
Issue number | 5 |
DOIs | |
State | Published - 1 Jan 1997 |
ID: 49763973