DOI

Three new layered copper hydrogen selenite nitrates, (ANO3)[Cu(HSeO3)2] (A = Cs, and Tl), and (RbNO3)2[Cu(HSeO3)2] have been prepared via isothermal evaporation of concentrated nitric acid solutions. The Tl and Cs compounds adopt a motif related to previously known (NH4Cl)[Cu(HSeO3)2]; the structure of the Rb compound represents a new structure type. The structures of (ANO3)[Cu(HSeO3)2] (A = Cs, Tl), (RbNO3)2[Cu(HSeO3)2], and (NH4NO3)3[Cu(HSeO3)2] form a unique homological series distantly related to Ruddlesden - Popper series of layered perovskites.

Original languageEnglish
JournalZeitschrift fur Kristallographie - Crystalline Materials
DOIs
StateE-pub ahead of print - 2019

    Research areas

  • copper, crystal engineering, layered materials, nitrates, selenites

    Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

ID: 53747621