Coordination Chemistry of Anionic Pnictogenylborane Compounds

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Coordination Chemistry of Anionic Pnictogenylborane Compounds. / Elsayed Moussa, Mehdi; Kahoun, Tobias; Ackermann, Matthias T.; Seidl, Michael; Bodensteiner, Michael; Timoshkin, Alexey Y.; Scheer, Manfred.

In: Organometallics, Vol. 41, No. 12, 27.06.2022, p. 1572-1578.

Research output: Contribution to journal › Article › peer-review

Harvard

Elsayed Moussa, M, Kahoun, T, Ackermann, MT, Seidl, M, Bodensteiner, M, Timoshkin, AY & Scheer, M 2022, 'Coordination Chemistry of Anionic Pnictogenylborane Compounds', Organometallics, vol. 41, no. 12, pp. 1572-1578. https://doi.org/10.1021/acs.organomet.2c00194

APA

Elsayed Moussa, M., Kahoun, T., Ackermann, M. T., Seidl, M., Bodensteiner, M., Timoshkin, A. Y., & Scheer, M. (2022). Coordination Chemistry of Anionic Pnictogenylborane Compounds. Organometallics, 41(12), 1572-1578. https://doi.org/10.1021/acs.organomet.2c00194

Vancouver

Elsayed Moussa M, Kahoun T, Ackermann MT, Seidl M, Bodensteiner M, Timoshkin AY et al. Coordination Chemistry of Anionic Pnictogenylborane Compounds. Organometallics. 2022 Jun 27;41(12):1572-1578. https://doi.org/10.1021/acs.organomet.2c00194

Author

Elsayed Moussa, Mehdi ; Kahoun, Tobias ; Ackermann, Matthias T. ; Seidl, Michael ; Bodensteiner, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred. / Coordination Chemistry of Anionic Pnictogenylborane Compounds. In: Organometallics. 2022 ; Vol. 41, No. 12. pp. 1572-1578.

BibTeX

@article{818683ea9dc64b85876e374023bc4f44,

title = "Coordination Chemistry of Anionic Pnictogenylborane Compounds",

abstract = "Novel anionic metallacycles (6: [(1) W(CO)4]; 7: ([(2) W(CO)4])2; 8: [(3) W(CO)4]; 9: [(4) W(CO)4]; and 10: [(5) W(CO)4]) were selectively synthesized from the reaction of the flexible anionic pnictogenylborane derivatives [M(C12H24O6)][H2E-BH2-EH2] [E = P, M = Na (1); E = As, M = K (2)], [Na(C12H24O6)][H2As-BH2-PH2-BH2-AsH2] (3), and [Na(C12H24O6)(thf)2][tBuHE-BH2-EHtBu] [E = P (4); E = As (5)], with [W(CO)4(nbd)] (nbd = bicyclo[2.2.1]hepta-2,5-diene). In addition, the reaction of 1, 4, and 5 with [Cu(MeCN)4][BF4] leads to unique coordination assemblies of the general formula [Cu2Na2(RHE-BH2-EHR)4]n[E = P, R = H (11); E = P, R = tBu (12); E = As, R = tBu (13)]. The solid-state structure of compound 11 possesses an inorganic 3D scaffold with an adamantane-like repeating unit of Cu(I) ions.",

author = "{Elsayed Moussa}, Mehdi and Tobias Kahoun and Ackermann, {Matthias T.} and Michael Seidl and Michael Bodensteiner and Timoshkin, {Alexey Y.} and Manfred Scheer",

year = "2022",

month = jun,

day = "27",

doi = "10.1021/acs.organomet.2c00194",

language = "English",

volume = "41",

pages = "1572--1578",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "12",

}

RIS

TY - JOUR

T1 - Coordination Chemistry of Anionic Pnictogenylborane Compounds

AU - Elsayed Moussa, Mehdi

AU - Kahoun, Tobias

AU - Ackermann, Matthias T.

AU - Seidl, Michael

AU - Bodensteiner, Michael

AU - Timoshkin, Alexey Y.

AU - Scheer, Manfred

PY - 2022/6/27

Y1 - 2022/6/27

N2 - Novel anionic metallacycles (6: [(1) W(CO)4]; 7: ([(2) W(CO)4])2; 8: [(3) W(CO)4]; 9: [(4) W(CO)4]; and 10: [(5) W(CO)4]) were selectively synthesized from the reaction of the flexible anionic pnictogenylborane derivatives [M(C12H24O6)][H2E-BH2-EH2] [E = P, M = Na (1); E = As, M = K (2)], [Na(C12H24O6)][H2As-BH2-PH2-BH2-AsH2] (3), and [Na(C12H24O6)(thf)2][tBuHE-BH2-EHtBu] [E = P (4); E = As (5)], with [W(CO)4(nbd)] (nbd = bicyclo[2.2.1]hepta-2,5-diene). In addition, the reaction of 1, 4, and 5 with [Cu(MeCN)4][BF4] leads to unique coordination assemblies of the general formula [Cu2Na2(RHE-BH2-EHR)4]n[E = P, R = H (11); E = P, R = tBu (12); E = As, R = tBu (13)]. The solid-state structure of compound 11 possesses an inorganic 3D scaffold with an adamantane-like repeating unit of Cu(I) ions.

AB - Novel anionic metallacycles (6: [(1) W(CO)4]; 7: ([(2) W(CO)4])2; 8: [(3) W(CO)4]; 9: [(4) W(CO)4]; and 10: [(5) W(CO)4]) were selectively synthesized from the reaction of the flexible anionic pnictogenylborane derivatives [M(C12H24O6)][H2E-BH2-EH2] [E = P, M = Na (1); E = As, M = K (2)], [Na(C12H24O6)][H2As-BH2-PH2-BH2-AsH2] (3), and [Na(C12H24O6)(thf)2][tBuHE-BH2-EHtBu] [E = P (4); E = As (5)], with [W(CO)4(nbd)] (nbd = bicyclo[2.2.1]hepta-2,5-diene). In addition, the reaction of 1, 4, and 5 with [Cu(MeCN)4][BF4] leads to unique coordination assemblies of the general formula [Cu2Na2(RHE-BH2-EHR)4]n[E = P, R = H (11); E = P, R = tBu (12); E = As, R = tBu (13)]. The solid-state structure of compound 11 possesses an inorganic 3D scaffold with an adamantane-like repeating unit of Cu(I) ions.

UR - http://www.scopus.com/inward/record.url?scp=85133538898&partnerID=8YFLogxK

U2 - 10.1021/acs.organomet.2c00194

DO - 10.1021/acs.organomet.2c00194

M3 - Article

AN - SCOPUS:85133538898

VL - 41

SP - 1572

EP - 1578

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 12

ER -

ID: 98488985