Research output: Contribution to journal › Article
Controllable p-doping of graphene on Ir(111) by chlorination with FeCl3. / Vinogradov, N.A.; Simonov, K.A.; Generalov, A.V.; Vinogradov, A.S.; Vyalikh, D.V.; C, Laubschat; Martensson, N.; Preobrajenski, AB .
In: Journal of Physics: Condensed Matter, Vol. 24, No. 31, 2012, p. 314202_1-8.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Controllable p-doping of graphene on Ir(111) by chlorination with FeCl3
AU - Vinogradov, N.A.
AU - Simonov, K.A.
AU - Generalov, A.V.
AU - Vinogradov, A.S.
AU - Vyalikh, D.V.
AU - C, Laubschat
AU - Martensson, N.
AU - Preobrajenski, AB
PY - 2012
Y1 - 2012
N2 - The in situ chlorination of graphene on Ir(111) has been achieved by depositing FeCl3 followed by its thermal decomposition on the surface into FeCl2 and Cl. This process is accompanied by an intercalation of Cl under graphene and formation of an epitaxial FeCl2 film on top, which can be removed upon further annealing. A pronounced hole doping of graphene has been observed as a consequence of the annealing-assisted intercalation of Cl. This effect has been studied by a combination of core-level and angle-resolved photoelectron spectroscopies (CL PES and ARPES, respectively), near-edge x-ray absorption fine structure (NEXAFS) spectroscopy and low-energy electron diffraction (LEED). The ease of preparation, the remarkable reproducibility of the doping level and the reversibility of the doping upon annealing are the key factors making chlorination with FeCl3 a promising route for tuning the electronic properties in graphene.
AB - The in situ chlorination of graphene on Ir(111) has been achieved by depositing FeCl3 followed by its thermal decomposition on the surface into FeCl2 and Cl. This process is accompanied by an intercalation of Cl under graphene and formation of an epitaxial FeCl2 film on top, which can be removed upon further annealing. A pronounced hole doping of graphene has been observed as a consequence of the annealing-assisted intercalation of Cl. This effect has been studied by a combination of core-level and angle-resolved photoelectron spectroscopies (CL PES and ARPES, respectively), near-edge x-ray absorption fine structure (NEXAFS) spectroscopy and low-energy electron diffraction (LEED). The ease of preparation, the remarkable reproducibility of the doping level and the reversibility of the doping upon annealing are the key factors making chlorination with FeCl3 a promising route for tuning the electronic properties in graphene.
U2 - 10.1088/0953-8984/24/31/314202
DO - 10.1088/0953-8984/24/31/314202
M3 - Article
VL - 24
SP - 314202_1-8
JO - Journal of Physics Condensed Matter
JF - Journal of Physics Condensed Matter
SN - 0953-8984
IS - 31
ER -
ID: 5345591