Research output: Contribution to journal › Article › peer-review
Constant Potential Coulometric Measurements with Ca2+ -Selective Electrode : Analysis Using Calibration Plot vs. Analysis Using the Charge Curve Fitting. / Bondar, Anna; Mikhelson, Konstantin.
In: Sensors, Vol. 22, No. 3, 1145, 02.02.2022.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Constant Potential Coulometric Measurements with Ca2+ -Selective Electrode
T2 - Analysis Using Calibration Plot vs. Analysis Using the Charge Curve Fitting
AU - Bondar, Anna
AU - Mikhelson, Konstantin
N1 - Bondar, A.; Mikhelson, K. Constant Potential Coulometric Measurements with Ca2+-Selective Electrode: Analysis Using Calibration Plot vs. Analysis Using the Charge Curve Fitting. Sensors 2022, 22, 1145. https://doi.org/10.3390/s22031145
PY - 2022/2/2
Y1 - 2022/2/2
N2 - The possibility of analysis using charge curve fitting in constant potential coulometric mode instead of using a calibration plot is explored, for the first time. The results are compared with the analysis based on the use of a calibration plot. A Ca2+ ion-selective electrode, with and without an electronic capacitor in series, is used as a model system in pure solutions of CaCl2. Both techniques delivered good results (error within 2%) when the final and the initial concentration values differed by not more than three times. Larger differences result in 10–25% error. The presence of an electronic capacitor in the measurement circuit and in series with the electrode, allows for signifi-cantly faster response.
AB - The possibility of analysis using charge curve fitting in constant potential coulometric mode instead of using a calibration plot is explored, for the first time. The results are compared with the analysis based on the use of a calibration plot. A Ca2+ ion-selective electrode, with and without an electronic capacitor in series, is used as a model system in pure solutions of CaCl2. Both techniques delivered good results (error within 2%) when the final and the initial concentration values differed by not more than three times. Larger differences result in 10–25% error. The presence of an electronic capacitor in the measurement circuit and in series with the electrode, allows for signifi-cantly faster response.
KW - Analysis
KW - Calcium ion activity
KW - Calibration plot
KW - Charge curve fitting
KW - Constant potential coulometry
KW - calcium ion activity
KW - MEMBRANES
KW - READOUT
KW - charge curve fitting
KW - analysis
KW - calibration plot
KW - constant potential coulometry
KW - BULK RESISTANCE
KW - ION-SELECTIVE ELECTRODES
UR - http://www.scopus.com/inward/record.url?scp=85123760717&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/0ba76650-8306-3a7a-901c-3691867acf4c/
U2 - 10.3390/s22031145
DO - 10.3390/s22031145
M3 - Article
AN - SCOPUS:85123760717
VL - 22
JO - Sensors
JF - Sensors
SN - 1424-3210
IS - 3
M1 - 1145
ER -
ID: 92357379