The hydrodynamic and conformational properties of silicon-containing polynorbornene prepared by metathesis polymerization of 5- trimethylsilylnorbornene in the presence of Grubbs Ru carbene complex were studied by viscometry, isothermal translation diffusion, and centrifugal sedimentation. For the ten-sample homologous series of the polymer, Mark-Kuhn-Houwink relationships correlating the hydrodynamic characteristics of the molecules in toluene with their molecular weight were obtained.

Original languageEnglish
Pages (from-to)2014-2020
Number of pages7
JournalRussian Journal of Applied Chemistry
Volume81
Issue number11
DOIs
StatePublished - Nov 2008

    Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

ID: 72112807