Research output: Contribution to journal › Article › peer-review
Concentrations of monomers and cylindrical micelles above the second CMC. / Kuni, F. M.; Shchekin, A. K.; Rusanov, A. I.; Grinin, A. P.
In: Colloid Journal, Vol. 66, No. 2, 01.03.2004, p. 174-185.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Concentrations of monomers and cylindrical micelles above the second CMC
AU - Kuni, F. M.
AU - Shchekin, A. K.
AU - Rusanov, A. I.
AU - Grinin, A. P.
PY - 2004/3/1
Y1 - 2004/3/1
N2 - The concentrations of cylindrical micelles and monomers above the second critical micellization concentration (CMC) were discussed. It was shown that the ratios of the total concentration were equal by the order of magnitude to 1 and 102 respectively. It was also shown that the second CMC exceeds the first CMC by two orders of magnitude, corresponding to the onset of the noticeable accumulation of surfactant in spherical micelles. It was analyzed that the total concentration of mean value, cylindrical micelles, and mean statistical scatter of aggregation numbers in a cylindrical micelle was proportional to the square root of the overall surfactant concentration.
AB - The concentrations of cylindrical micelles and monomers above the second critical micellization concentration (CMC) were discussed. It was shown that the ratios of the total concentration were equal by the order of magnitude to 1 and 102 respectively. It was also shown that the second CMC exceeds the first CMC by two orders of magnitude, corresponding to the onset of the noticeable accumulation of surfactant in spherical micelles. It was analyzed that the total concentration of mean value, cylindrical micelles, and mean statistical scatter of aggregation numbers in a cylindrical micelle was proportional to the square root of the overall surfactant concentration.
UR - http://www.scopus.com/inward/record.url?scp=3543126003&partnerID=8YFLogxK
U2 - 10.1023/B:COLL.0000023118.39776.e4
DO - 10.1023/B:COLL.0000023118.39776.e4
M3 - Article
AN - SCOPUS:3543126003
VL - 66
SP - 174
EP - 185
JO - Colloid Journal
JF - Colloid Journal
SN - 1061-933X
IS - 2
ER -
ID: 26000355