Research output: Contribution to journal › Article › peer-review
Complex Uranyl Dichromates Templated by Aza-Crowns. / Siidra, Oleg I.; Nazarchuk, Evgeny V.; Charkin, Dmitry O.; Kalmykov, Stepan N.; Zadoya, Anastasiya I.
In: Crystals, Vol. 8, 12.2018, p. 462.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Complex Uranyl Dichromates Templated by Aza-Crowns
AU - Siidra, Oleg I.
AU - Nazarchuk, Evgeny V.
AU - Charkin, Dmitry O.
AU - Kalmykov, Stepan N.
AU - Zadoya, Anastasiya I.
PY - 2018/12
Y1 - 2018/12
N2 - Three new uranyl dichromate compounds templated by aza-crown templates were obtained at room temperature by evaporation from aqueous solutions: 4 (3). The use of aza-crown templates made it possible to isolate unprecedented and complex one-dimensional units in 2 and 3, whereas the structure of 1 is based on simple uranyl-dichromate chains. It is very likely that the presence of relatively large organic molecules of aza-crown ethers does not allow uranyl chromate chain complexes to condense into the units of higher dimensionality (layers or frameworks). In general, the formation of 1, 2, and 3 is in agreement with the general principles elaborated for organically templated uranyl compounds. The negative charge of the [(UO 2)(Cr 2 O 7) 2 (H 2 O)] 2− , [(UO 2) 2 (CrO 4) 2 (Cr 2 O 7) 2 (H 2 O)] 4− and [(UO 2) 3 (CrO 4) 4 (Cr 2 O 7) 2 ] 6− one-dimensional inorganic motifs is compensated by the protonation of all nitrogen atoms in the molecules of aza-crowns.
AB - Three new uranyl dichromate compounds templated by aza-crown templates were obtained at room temperature by evaporation from aqueous solutions: 4 (3). The use of aza-crown templates made it possible to isolate unprecedented and complex one-dimensional units in 2 and 3, whereas the structure of 1 is based on simple uranyl-dichromate chains. It is very likely that the presence of relatively large organic molecules of aza-crown ethers does not allow uranyl chromate chain complexes to condense into the units of higher dimensionality (layers or frameworks). In general, the formation of 1, 2, and 3 is in agreement with the general principles elaborated for organically templated uranyl compounds. The negative charge of the [(UO 2)(Cr 2 O 7) 2 (H 2 O)] 2− , [(UO 2) 2 (CrO 4) 2 (Cr 2 O 7) 2 (H 2 O)] 4− and [(UO 2) 3 (CrO 4) 4 (Cr 2 O 7) 2 ] 6− one-dimensional inorganic motifs is compensated by the protonation of all nitrogen atoms in the molecules of aza-crowns.
M3 - Article
VL - 8
SP - 462
JO - Liquid Crystals Today
JF - Liquid Crystals Today
SN - 1358-314X
ER -
ID: 36551052