Standard

Comparative NEXAFS, NMR and FTIR Study of Various-sized Nanodiamonds – As-prepared and Fluorinated. / Zagrebina, E.M.; Generalov, A.V.; Klyushin, A.Y.; Simonov, K.A.; Vinogradov, N.A.; Dubois, M.; Frezet, L.; M rtensson, N.; Preobrajenski, A.B.; Vinogradov, A.S.

In: Journal of Physical Chemistry C, Vol. 119, No. 1, 2015, p. 835-844.

Research output: Contribution to journal › Article › peer-review

Harvard

Zagrebina, EM, Generalov, AV, Klyushin, AY, Simonov, KA, Vinogradov, NA, Dubois, M, Frezet, L, M rtensson, N, Preobrajenski, AB & Vinogradov, AS 2015, 'Comparative NEXAFS, NMR and FTIR Study of Various-sized Nanodiamonds – As-prepared and Fluorinated', Journal of Physical Chemistry C, vol. 119, no. 1, pp. 835-844. https://doi.org/10.1021/jp510618s

APA

Zagrebina, E. M., Generalov, A. V., Klyushin, A. Y., Simonov, K. A., Vinogradov, N. A., Dubois, M., Frezet, L., M rtensson, N., Preobrajenski, A. B., & Vinogradov, A. S. (2015). Comparative NEXAFS, NMR and FTIR Study of Various-sized Nanodiamonds – As-prepared and Fluorinated. Journal of Physical Chemistry C, 119(1), 835-844. https://doi.org/10.1021/jp510618s

Vancouver

Zagrebina EM, Generalov AV, Klyushin AY, Simonov KA, Vinogradov NA, Dubois M et al. Comparative NEXAFS, NMR and FTIR Study of Various-sized Nanodiamonds – As-prepared and Fluorinated. Journal of Physical Chemistry C. 2015;119(1):835-844. https://doi.org/10.1021/jp510618s

Author

Zagrebina, E.M. ; Generalov, A.V. ; Klyushin, A.Y. ; Simonov, K.A. ; Vinogradov, N.A. ; Dubois, M. ; Frezet, L. ; M rtensson, N. ; Preobrajenski, A.B. ; Vinogradov, A.S. / Comparative NEXAFS, NMR and FTIR Study of Various-sized Nanodiamonds – As-prepared and Fluorinated. In: Journal of Physical Chemistry C. 2015 ; Vol. 119, No. 1. pp. 835-844.

BibTeX

@article{32f0528ac786418b88276b22eae52520,
title = "Comparative NEXAFS, NMR and FTIR Study of Various-sized Nanodiamonds – As-prepared and Fluorinated",
abstract = "Various 4−50 nm in size diamond nanoparticles prepared by different synthesis methods and their fluorinated derivatives were studied by NEXAFS, solid state NMR and FTIR spectroscopy. C 1s and F 1s NEXAFS spectra of as-prepared and fluorinated nanodiamonds (NDs and F-NDs) were analyzed based on a comparison with the known ones of reference compounds (graphitized carbon nanodiscs, phenol and amino acid molecules, graphite oxide and monofluoride). It has been found that all the studied diamond nanoparticles have crystalline diamond cores and their surfaces are covered with graphite-like carbon clusters. These clusters are partially amorphized and oxidized with the formation of functional groups C−OH, C=O, or O=C−OH and the properties of these surface shells depend on the synthesis method of nanodiamonds. The fluorination of diamond nanoparticles has a purely superficial character; it almost completely cleans the NDs particles from carbon clusters and saturates dangling bonds on the surface of the diamond nanoparticle",
author = "E.M. Zagrebina and A.V. Generalov and A.Y. Klyushin and K.A. Simonov and N.A. Vinogradov and M. Dubois and L. Frezet and {M rtensson}, N. and A.B. Preobrajenski and A.S. Vinogradov",
year = "2015",
doi = "10.1021/jp510618s",
language = "English",
volume = "119",
pages = "835--844",
journal = "Journal of Physical Chemistry C",
issn = "1932-7447",
publisher = "American Chemical Society",
number = "1",

}

RIS

TY - JOUR

T1 - Comparative NEXAFS, NMR and FTIR Study of Various-sized Nanodiamonds – As-prepared and Fluorinated

AU - Zagrebina, E.M.

AU - Generalov, A.V.

AU - Klyushin, A.Y.

AU - Simonov, K.A.

AU - Vinogradov, N.A.

AU - Dubois, M.

AU - Frezet, L.

AU - M rtensson, N.

AU - Preobrajenski, A.B.

AU - Vinogradov, A.S.

PY - 2015

Y1 - 2015

N2 - Various 4−50 nm in size diamond nanoparticles prepared by different synthesis methods and their fluorinated derivatives were studied by NEXAFS, solid state NMR and FTIR spectroscopy. C 1s and F 1s NEXAFS spectra of as-prepared and fluorinated nanodiamonds (NDs and F-NDs) were analyzed based on a comparison with the known ones of reference compounds (graphitized carbon nanodiscs, phenol and amino acid molecules, graphite oxide and monofluoride). It has been found that all the studied diamond nanoparticles have crystalline diamond cores and their surfaces are covered with graphite-like carbon clusters. These clusters are partially amorphized and oxidized with the formation of functional groups C−OH, C=O, or O=C−OH and the properties of these surface shells depend on the synthesis method of nanodiamonds. The fluorination of diamond nanoparticles has a purely superficial character; it almost completely cleans the NDs particles from carbon clusters and saturates dangling bonds on the surface of the diamond nanoparticle

AB - Various 4−50 nm in size diamond nanoparticles prepared by different synthesis methods and their fluorinated derivatives were studied by NEXAFS, solid state NMR and FTIR spectroscopy. C 1s and F 1s NEXAFS spectra of as-prepared and fluorinated nanodiamonds (NDs and F-NDs) were analyzed based on a comparison with the known ones of reference compounds (graphitized carbon nanodiscs, phenol and amino acid molecules, graphite oxide and monofluoride). It has been found that all the studied diamond nanoparticles have crystalline diamond cores and their surfaces are covered with graphite-like carbon clusters. These clusters are partially amorphized and oxidized with the formation of functional groups C−OH, C=O, or O=C−OH and the properties of these surface shells depend on the synthesis method of nanodiamonds. The fluorination of diamond nanoparticles has a purely superficial character; it almost completely cleans the NDs particles from carbon clusters and saturates dangling bonds on the surface of the diamond nanoparticle

U2 - 10.1021/jp510618s

DO - 10.1021/jp510618s

M3 - Article

VL - 119

SP - 835

EP - 844

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

SN - 1932-7447

IS - 1

ER -

ID: 3937977