Research output: Contribution to journal › Letter › peer-review
Comment on “Intermolecular translational-rotational contribution to nuclear-spin relaxation in liquids”. / Skrynnikov, N. R.
In: Physical Review A - Atomic, Molecular, and Optical Physics, Vol. 53, No. 6, 1996, p. 4611-4612.Research output: Contribution to journal › Letter › peer-review
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TY - JOUR
T1 - Comment on “Intermolecular translational-rotational contribution to nuclear-spin relaxation in liquids”
AU - Skrynnikov, N. R.
PY - 1996
Y1 - 1996
N2 - A recent theoretical treatment of intermolecular nuclear-spin relaxation that incorporates the effect of molecular rotation [K. Lendi, Phys. Rev. A 45, 7906 (1992)] is shown to be based on what appears to be a mistaken assignment of Euler angles. In particular, the conditional probability for reorientation of the intermolecular vector due to molecular rotation seems to be given incorrectly. Unsolvable integrals that are examined by Lendi are derived without considering the reflecting wall boundary conditions that are requisite for the problem of translational diffusion.
AB - A recent theoretical treatment of intermolecular nuclear-spin relaxation that incorporates the effect of molecular rotation [K. Lendi, Phys. Rev. A 45, 7906 (1992)] is shown to be based on what appears to be a mistaken assignment of Euler angles. In particular, the conditional probability for reorientation of the intermolecular vector due to molecular rotation seems to be given incorrectly. Unsolvable integrals that are examined by Lendi are derived without considering the reflecting wall boundary conditions that are requisite for the problem of translational diffusion.
UR - http://www.scopus.com/inward/record.url?scp=6244240131&partnerID=8YFLogxK
U2 - 10.1103/PhysRevA.53.4611
DO - 10.1103/PhysRevA.53.4611
M3 - Letter
AN - SCOPUS:6244240131
VL - 53
SP - 4611
EP - 4612
JO - Physical Review A - Atomic, Molecular, and Optical Physics
JF - Physical Review A - Atomic, Molecular, and Optical Physics
SN - 1050-2947
IS - 6
ER -
ID: 87883805