The present atomic theory provides accurate and reliable results for atoms with a small number of valence electrons. However, most current methods of calculations fail when the number of valence electrons exceeds four or five. This means that we cannot make reliable predictions for more than half of the periodic table. Here we suggest a modification of the configuration interaction plus many-body perturbation theory, which may be applicable to atoms and ions with partly filled d and f shells.

Translated title of the contributionКомбинированный метод теории возмущений и взаимодействие конфигураций
Original languageEnglish
Article number052805
Number of pages10
JournalPhysical Review A
Volume105
Issue number5
DOIs
StatePublished - May 2022

    Scopus subject areas

  • Atomic and Molecular Physics, and Optics

ID: 100693817