Colloidal properties of polymerizable counterion surfmers solutions based on alkylamino 2-acrylamido-2-methylpropanesulfonates in different solvents

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Colloidal properties of polymerizable counterion surfmers solutions based on alkylamino 2-acrylamido-2-methylpropanesulfonates in different solvents. / Bilibin, A. Yu ; Shcherbinina, T. M.; Girbasova, N. V.; Lebedev, V. T.; Kulvelis, Yu V.; Molchanov, V. S.; Zorin, I. M.

In: Designed Monomers and Polymers, Vol. 19, No. 5, 03.07.2016, p. 369-380.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{b13d205abaf546ccaa2f5cd06dbd4fb3,

title = "Colloidal properties of polymerizable counterion surfmers solutions based on alkylamino 2-acrylamido-2-methylpropanesulfonates in different solvents",

abstract = "Three polymerizable surfactants (surfmers) bearing 2-acrylamido-2-methylpropanesulfonic acid (AMPS) as polymerizable group in the counterion have been designed, synthesized, and their micelle-forming properties have been investigated in different solvents. Solutions of dodecylammonium (DDA-AMPS), cetylammonium (CA-AMPS), and cetyltrimethylammonium (CTA-AMPS) 2-acrylamido-2-methylpropanesulfonates were studied in water, water-dioxane mixtures in a whole range of components ratios, and xylene. The solutions were investigated by capillary and rotational viscometry, conductometry, and small-angle neutron scattering; aggregates adsorbed from the solutions on as-split mica were studied by atomic force microscopy (AFM). The surfmers follow general regularities of surfactant behavior in aqueous solutions. Decrease in polarity of the media with an increase in dioxane content in water-dioxane mixtures leads to disappearance of direct micelles. At low water content (below 5%) the surfmers form reverse micelles in the mixtures. The surfmers form reverse micelles in low polarity solvents, such as xylene, which should affect the polymerization results.",

keywords = "counterion, Micelle formation, micelles, polarity, polymerizable surfactants, solvents",

author = "Bilibin, {A. Yu} and Shcherbinina, {T. M.} and Girbasova, {N. V.} and Lebedev, {V. T.} and Kulvelis, {Yu V.} and Molchanov, {V. S.} and Zorin, {I. M.}",

note = "Publisher Copyright: {\textcopyright} 2016 Informa UK Limited, trading as Taylor & Francis Group.",

year = "2016",

month = jul,

day = "3",

doi = "10.1080/15685551.2016.1169371",

language = "English",

volume = "19",

pages = "369--380",

journal = "Designed Monomers and Polymers",

issn = "1385-772X",

publisher = "Taylor & Francis",

number = "5",

}

RIS

TY - JOUR

T1 - Colloidal properties of polymerizable counterion surfmers solutions based on alkylamino 2-acrylamido-2-methylpropanesulfonates in different solvents

AU - Bilibin, A. Yu

AU - Shcherbinina, T. M.

AU - Girbasova, N. V.

AU - Lebedev, V. T.

AU - Kulvelis, Yu V.

AU - Molchanov, V. S.

AU - Zorin, I. M.

PY - 2016/7/3

Y1 - 2016/7/3

N2 - Three polymerizable surfactants (surfmers) bearing 2-acrylamido-2-methylpropanesulfonic acid (AMPS) as polymerizable group in the counterion have been designed, synthesized, and their micelle-forming properties have been investigated in different solvents. Solutions of dodecylammonium (DDA-AMPS), cetylammonium (CA-AMPS), and cetyltrimethylammonium (CTA-AMPS) 2-acrylamido-2-methylpropanesulfonates were studied in water, water-dioxane mixtures in a whole range of components ratios, and xylene. The solutions were investigated by capillary and rotational viscometry, conductometry, and small-angle neutron scattering; aggregates adsorbed from the solutions on as-split mica were studied by atomic force microscopy (AFM). The surfmers follow general regularities of surfactant behavior in aqueous solutions. Decrease in polarity of the media with an increase in dioxane content in water-dioxane mixtures leads to disappearance of direct micelles. At low water content (below 5%) the surfmers form reverse micelles in the mixtures. The surfmers form reverse micelles in low polarity solvents, such as xylene, which should affect the polymerization results.

AB - Three polymerizable surfactants (surfmers) bearing 2-acrylamido-2-methylpropanesulfonic acid (AMPS) as polymerizable group in the counterion have been designed, synthesized, and their micelle-forming properties have been investigated in different solvents. Solutions of dodecylammonium (DDA-AMPS), cetylammonium (CA-AMPS), and cetyltrimethylammonium (CTA-AMPS) 2-acrylamido-2-methylpropanesulfonates were studied in water, water-dioxane mixtures in a whole range of components ratios, and xylene. The solutions were investigated by capillary and rotational viscometry, conductometry, and small-angle neutron scattering; aggregates adsorbed from the solutions on as-split mica were studied by atomic force microscopy (AFM). The surfmers follow general regularities of surfactant behavior in aqueous solutions. Decrease in polarity of the media with an increase in dioxane content in water-dioxane mixtures leads to disappearance of direct micelles. At low water content (below 5%) the surfmers form reverse micelles in the mixtures. The surfmers form reverse micelles in low polarity solvents, such as xylene, which should affect the polymerization results.

KW - counterion

KW - Micelle formation

KW - micelles

KW - polarity

KW - polymerizable surfactants

KW - solvents

UR - http://www.scopus.com/inward/record.url?scp=84963611949&partnerID=8YFLogxK

U2 - 10.1080/15685551.2016.1169371

DO - 10.1080/15685551.2016.1169371

M3 - Article

AN - SCOPUS:84963611949

VL - 19

SP - 369

EP - 380

JO - Designed Monomers and Polymers

JF - Designed Monomers and Polymers

SN - 1385-772X

IS - 5

ER -

ID: 99379806