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@article{5f61a7ee870e449db7ca6978450658c5,
title = "Colloid solution of surfactant monomers and polyelectrolyte: Polymerization and properties of the resulting interpolyelectrolyte complexes",
abstract = "In the present work, we suggest a novel method for obtaining interpolyelectrolyte complex (IPEC) by free radical polymerization in water–salt dispersions of polyelectrolyte complexes (PECs) based on an anionic polyelectrolyte (sodium salt of poly (2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS-Na)) and a cationic surfactant ((11-acryloyloxy) undecyl)-trimethylammonium bromide (AUTAB), as well as on PAUTAB cationic comb-like polyelectrolyte and AMPS-Na monomer. IPEC consisting of PAMPS and PAUTAB was obtained by two ways. The first one is polymerization of surface active monomers AUTAB in the presence of PAMPS, and the second one is polymerization of AMPS monomers in the presence of PAUTAB. Molecular hydrodynamics methods were used to determine the molecular properties of initial components, polyelectrolyte complexes (PECs), and IPECs. Analysis of the dependence between translational friction coefficient of macromolecules and their molecular masses (which takes into account excluded-volume effects) allow",
keywords = "Surfactant monomer, Self-assembly, Polyelectrolyte",
author = "N.V. Tsvetkov and P.A. Fetin and A.A. Lezov and A.S. Gubarev and L.I. Achmadeeva and A.A. Lezova and I.M. Zorin and A.Yu. Bilibin",
year = "2015",
doi = "10.1016/j.molliq.2015.07.003",
language = "English",
volume = "211",
pages = "239--246",
journal = "Journal of Molecular Liquids",
issn = "0167-7322",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Colloid solution of surfactant monomers and polyelectrolyte: Polymerization and properties of the resulting interpolyelectrolyte complexes

AU - Tsvetkov, N.V.

AU - Fetin, P.A.

AU - Lezov, A.A.

AU - Gubarev, A.S.

AU - Achmadeeva, L.I.

AU - Lezova, A.A.

AU - Zorin, I.M.

AU - Bilibin, A.Yu.

PY - 2015

Y1 - 2015

N2 - In the present work, we suggest a novel method for obtaining interpolyelectrolyte complex (IPEC) by free radical polymerization in water–salt dispersions of polyelectrolyte complexes (PECs) based on an anionic polyelectrolyte (sodium salt of poly (2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS-Na)) and a cationic surfactant ((11-acryloyloxy) undecyl)-trimethylammonium bromide (AUTAB), as well as on PAUTAB cationic comb-like polyelectrolyte and AMPS-Na monomer. IPEC consisting of PAMPS and PAUTAB was obtained by two ways. The first one is polymerization of surface active monomers AUTAB in the presence of PAMPS, and the second one is polymerization of AMPS monomers in the presence of PAUTAB. Molecular hydrodynamics methods were used to determine the molecular properties of initial components, polyelectrolyte complexes (PECs), and IPECs. Analysis of the dependence between translational friction coefficient of macromolecules and their molecular masses (which takes into account excluded-volume effects) allow

AB - In the present work, we suggest a novel method for obtaining interpolyelectrolyte complex (IPEC) by free radical polymerization in water–salt dispersions of polyelectrolyte complexes (PECs) based on an anionic polyelectrolyte (sodium salt of poly (2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS-Na)) and a cationic surfactant ((11-acryloyloxy) undecyl)-trimethylammonium bromide (AUTAB), as well as on PAUTAB cationic comb-like polyelectrolyte and AMPS-Na monomer. IPEC consisting of PAMPS and PAUTAB was obtained by two ways. The first one is polymerization of surface active monomers AUTAB in the presence of PAMPS, and the second one is polymerization of AMPS monomers in the presence of PAUTAB. Molecular hydrodynamics methods were used to determine the molecular properties of initial components, polyelectrolyte complexes (PECs), and IPECs. Analysis of the dependence between translational friction coefficient of macromolecules and their molecular masses (which takes into account excluded-volume effects) allow

KW - Surfactant monomer

KW - Self-assembly

KW - Polyelectrolyte

U2 - 10.1016/j.molliq.2015.07.003

DO - 10.1016/j.molliq.2015.07.003

M3 - Article

VL - 211

SP - 239

EP - 246

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

SN - 0167-7322

ER -

ID: 3938688