Research output: Contribution to journal › Article
Colloid solution of surfactant monomers and polyelectrolyte: Polymerization and properties of the resulting interpolyelectrolyte complexes. / Tsvetkov, N.V.; Fetin, P.A.; Lezov, A.A.; Gubarev, A.S.; Achmadeeva, L.I.; Lezova, A.A.; Zorin, I.M.; Bilibin, A.Yu.
In: Journal of Molecular Liquids, Vol. 211, 2015, p. 239-246.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Colloid solution of surfactant monomers and polyelectrolyte: Polymerization and properties of the resulting interpolyelectrolyte complexes
AU - Tsvetkov, N.V.
AU - Fetin, P.A.
AU - Lezov, A.A.
AU - Gubarev, A.S.
AU - Achmadeeva, L.I.
AU - Lezova, A.A.
AU - Zorin, I.M.
AU - Bilibin, A.Yu.
PY - 2015
Y1 - 2015
N2 - In the present work, we suggest a novel method for obtaining interpolyelectrolyte complex (IPEC) by free radical polymerization in water–salt dispersions of polyelectrolyte complexes (PECs) based on an anionic polyelectrolyte (sodium salt of poly (2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS-Na)) and a cationic surfactant ((11-acryloyloxy) undecyl)-trimethylammonium bromide (AUTAB), as well as on PAUTAB cationic comb-like polyelectrolyte and AMPS-Na monomer. IPEC consisting of PAMPS and PAUTAB was obtained by two ways. The first one is polymerization of surface active monomers AUTAB in the presence of PAMPS, and the second one is polymerization of AMPS monomers in the presence of PAUTAB. Molecular hydrodynamics methods were used to determine the molecular properties of initial components, polyelectrolyte complexes (PECs), and IPECs. Analysis of the dependence between translational friction coefficient of macromolecules and their molecular masses (which takes into account excluded-volume effects) allow
AB - In the present work, we suggest a novel method for obtaining interpolyelectrolyte complex (IPEC) by free radical polymerization in water–salt dispersions of polyelectrolyte complexes (PECs) based on an anionic polyelectrolyte (sodium salt of poly (2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS-Na)) and a cationic surfactant ((11-acryloyloxy) undecyl)-trimethylammonium bromide (AUTAB), as well as on PAUTAB cationic comb-like polyelectrolyte and AMPS-Na monomer. IPEC consisting of PAMPS and PAUTAB was obtained by two ways. The first one is polymerization of surface active monomers AUTAB in the presence of PAMPS, and the second one is polymerization of AMPS monomers in the presence of PAUTAB. Molecular hydrodynamics methods were used to determine the molecular properties of initial components, polyelectrolyte complexes (PECs), and IPECs. Analysis of the dependence between translational friction coefficient of macromolecules and their molecular masses (which takes into account excluded-volume effects) allow
KW - Surfactant monomer
KW - Self-assembly
KW - Polyelectrolyte
U2 - 10.1016/j.molliq.2015.07.003
DO - 10.1016/j.molliq.2015.07.003
M3 - Article
VL - 211
SP - 239
EP - 246
JO - Journal of Molecular Liquids
JF - Journal of Molecular Liquids
SN - 0167-7322
ER -
ID: 3938688