Research output: Contribution to journal › Article › peer-review
Colloid chemical characteristics of nanoporous glasses with different compositions in solutions of simple and organic electrolytes. 3. Calculation of electrochemical characteristics of membranes in terms of a homogeneous model. / Ermakova, L. E.; Volkova, A. V.
In: Colloid Journal, Vol. 79, No. 4, 01.07.2017, p. 459-473.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Colloid chemical characteristics of nanoporous glasses with different compositions in solutions of simple and organic electrolytes. 3. Calculation of electrochemical characteristics of membranes in terms of a homogeneous model
AU - Ermakova, L. E.
AU - Volkova, A. V.
PY - 2017/7/1
Y1 - 2017/7/1
N2 - The electrosurface characteristics of nanoporous glass membranes–ion concentrations in pores with taking into account the specificity of counterions, electrokinetically mobile charge, the convective component of pore solution electrical conductivity, electroosmotic mobility of a liquid in the field of streaming potential and ion mobilities in pore space–were calculated within the homogeneous model. The effects of the type of counterion (sodium, potassium, ammonium, tetramethylammonium, and tetraethylammonium ions), solution concentration, glass composition, and pore size on the equilibrium and transport characteristics of membrane systems have been analyzed. A method for the determining of electrolyte activity coefficients in the membranes has been proposed.
AB - The electrosurface characteristics of nanoporous glass membranes–ion concentrations in pores with taking into account the specificity of counterions, electrokinetically mobile charge, the convective component of pore solution electrical conductivity, electroosmotic mobility of a liquid in the field of streaming potential and ion mobilities in pore space–were calculated within the homogeneous model. The effects of the type of counterion (sodium, potassium, ammonium, tetramethylammonium, and tetraethylammonium ions), solution concentration, glass composition, and pore size on the equilibrium and transport characteristics of membrane systems have been analyzed. A method for the determining of electrolyte activity coefficients in the membranes has been proposed.
UR - http://www.scopus.com/inward/record.url?scp=85026755208&partnerID=8YFLogxK
U2 - 10.1134/S1061933X17040032
DO - 10.1134/S1061933X17040032
M3 - Article
AN - SCOPUS:85026755208
VL - 79
SP - 459
EP - 473
JO - Colloid Journal
JF - Colloid Journal
SN - 1061-933X
IS - 4
ER -
ID: 9371203