Research output: Contribution to journal › Article › peer-review
Coagulation of aqueous nanodisperse graphite suspensions in the presence of multivalent ions. / Petrov, M.P.; Vezo, O.S.; Trusov, A.A.; Voitylov, A.V.; Vojtylov, V.V.
In: Diamond and Related Materials, Vol. 101, 107599, 2020.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Coagulation of aqueous nanodisperse graphite suspensions in the presence of multivalent ions
AU - Petrov, M.P.
AU - Vezo, O.S.
AU - Trusov, A.A.
AU - Voitylov, A.V.
AU - Vojtylov, V.V.
N1 - M.P. Petrov, et al., Diamond & Related Materials, https://doi.org/10.1016/j.diamond.2019.107599
PY - 2020
Y1 - 2020
N2 - The results of the study of the coagulation kinetics of graphite nanoparticle suspensions in aqueous AlCl 3 and Th(NO 3) 4 electrolytes are presented. Electro-optical effects in disperse systems containing graphite particles allow to reliably investigate the coagulation kinetics in such systems. A method based on the analysis of changes of electro-optical effect relaxation dependencies in the process of coagulation was developed. The dependencies of the electrokinetic potential on the concentration of electrolytes are presented. Coagulation in such systems is observed if electrokinetic potential of graphite particles does not exceed 5 mV. At the isoelectric point, the fast coagulation theory is in good agreement with the observed processes of formation of aggregates from graphite particles. The conducted studies confirm the conclusion that the formation of aggregates from graphite particles with lyophobic surface is mainly influenced by the valence of the ions that determine the surface charge, and their other characteristics are of secondary importance.
AB - The results of the study of the coagulation kinetics of graphite nanoparticle suspensions in aqueous AlCl 3 and Th(NO 3) 4 electrolytes are presented. Electro-optical effects in disperse systems containing graphite particles allow to reliably investigate the coagulation kinetics in such systems. A method based on the analysis of changes of electro-optical effect relaxation dependencies in the process of coagulation was developed. The dependencies of the electrokinetic potential on the concentration of electrolytes are presented. Coagulation in such systems is observed if electrokinetic potential of graphite particles does not exceed 5 mV. At the isoelectric point, the fast coagulation theory is in good agreement with the observed processes of formation of aggregates from graphite particles. The conducted studies confirm the conclusion that the formation of aggregates from graphite particles with lyophobic surface is mainly influenced by the valence of the ions that determine the surface charge, and their other characteristics are of secondary importance.
KW - System dynamics
KW - Nanographite
KW - Coagulation
KW - Electrokinetic potential
KW - Electro-optical properties
KW - (D) System dynamics
KW - Coagulation
KW - Electro-optical properties
KW - Electrokinetic potential
KW - Nanographite
UR - http://www.scopus.com/inward/record.url?scp=85075384458&partnerID=8YFLogxK
U2 - 10.1016/j.diamond.2019.107599
DO - 10.1016/j.diamond.2019.107599
M3 - Article
VL - 101
JO - Diamond and Related Materials
JF - Diamond and Related Materials
SN - 0925-9635
M1 - 107599
ER -
ID: 48690897