Broadband spectra of the continuum absorption in pure CO2 gas and its mixture with Ar are studied at room temperature using a resonator spectrometer within 105–240 GHz. The expected pressure and frequency dependence is observed. The obtained data are validated by two independent calculations of the interaction-induced absorption using a semiclassical trajectory-based method. The observed continuum is interpreted in terms of bimolecular absorption, including a significant contribution from true bound dimers. A simplified formula describing both frequency and temperature dependency of the CO2–Ar continuum within a frequency range from 60 GHz to 450 GHz at temperatures from 200 K to 400 K is suggested for use in atmospheric studies.

Original languageEnglish
Article number107400
Number of pages10
JournalJournal of Quantitative Spectroscopy and Radiative Transfer
Volume258
DOIs
StatePublished - Jan 2021

    Scopus subject areas

  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Spectroscopy

    Research areas

  • Bimolecular absorption, Carbon dioxide, Classical trajectories, Continuum, Dimers, Resonator spectroscopy, Rototranslational band, COLLISION-INDUCED ABSORPTION, 239 GHZ, TEMPERATURE-VARIATIONS, FREE STATES, REGION, SPECTROSCOPY, WATER-VAPOR CONTINUUM, COMPRESSED GASES, INDUCED MICROWAVE-ABSORPTION, CARBON-DIOXIDE

ID: 73913288