DOI

  • Andrey N. Usoltsev
  • Sergey A. Adonin
  • Alexander S. Novikov
  • Pavel A. Abramov
  • Maxim N. Sokolov
  • Vladimir P. Fedin

Reactions of chlorotellurates(iv) and Br2 afford formation of one-dimensional supramolecular complexes of general formula Cat2{[TeCl6](Br2)} (Cat = Me3N+ (1), PyH+ (2), 4-MePyH+ (3) and 1-MePy+ (4)) where dibromine fragments are "trapped" by [TeCl6]3-via specific Br⋯Cl interactions (halogen bonding). The energies of the latter were estimated by DFT calculations (up to 5.7 kcal mol-1).

Original languageEnglish
Pages (from-to)1985-1990
Number of pages6
JournalCrystEngComm
Volume22
Issue number11
Early online date6 Feb 2020
DOIs
StatePublished - 21 Mar 2020

    Research areas

  • ZETA BASIS-SETS, PHENYLTRIMETHYLAMMONIUM SALTS, MOLECULAR-STRUCTURE, BOND DONOR, CENTER-DOT, COMPLEXES, BROMINE, INTERPLAY, NETWORKS, STABILIZATION

    Scopus subject areas

  • Condensed Matter Physics
  • Chemistry(all)
  • Materials Science(all)

ID: 52885094