Chemical equilibrium and liquid-phase splitting in acetic acid + n-propanol + n-propyl acetate + water system at 293.15 and 353.15 K

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Chemical equilibrium and liquid-phase splitting in acetic acid + n-propanol + n-propyl acetate + water system at 293.15 and 353.15 K. / Samarov, A. A.; Toikka, M. A.; Naumkin, P. V.; Toikka, A. M.

In: Theoretical Foundations of Chemical Engineering, Vol. 50, No. 5, 01.09.2016, p. 739-745.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{ac88ad93b0f34839923dbb8e5e997fd2,

title = "Chemical equilibrium and liquid-phase splitting in acetic acid + n-propanol + n-propyl acetate + water system at 293.15 and 353.15 K",

abstract = "The paper presents new experimental data on the chemical equilibrium in the system n-propanol + acetic acid + n-propyl acetate + water at 293.15 and 353.15 K, and the data on liquid–liquid equilibrium at 353.15 K. Based on the experimental and literature data, the possibilities that chemical equilibrium exists in a homogeneous or heterogeneous region of compositions has been analyzed. The temperature shift of chemical and phase equilibria and the values of the thermodynamic constants of chemical equilibrium are discussed.",

keywords = "chemical equilibrium, equilibrium constant, liquid–liquid equilibrium, n-propyl acetate, splitting",

author = "Samarov, {A. A.} and Toikka, {M. A.} and Naumkin, {P. V.} and Toikka, {A. M.}",

note = "Publisher Copyright: {\textcopyright} 2016, Pleiades Publishing, Ltd.",

year = "2016",

month = sep,

day = "1",

doi = "10.1134/S0040579516050377",

language = "English",

volume = "50",

pages = "739--745",

journal = "Theoretical Foundations of Chemical Engineering",

issn = "0040-5795",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "5",

}

RIS

TY - JOUR

T1 - Chemical equilibrium and liquid-phase splitting in acetic acid + n-propanol + n-propyl acetate + water system at 293.15 and 353.15 K

AU - Samarov, A. A.

AU - Toikka, M. A.

AU - Naumkin, P. V.

AU - Toikka, A. M.

PY - 2016/9/1

Y1 - 2016/9/1

N2 - The paper presents new experimental data on the chemical equilibrium in the system n-propanol + acetic acid + n-propyl acetate + water at 293.15 and 353.15 K, and the data on liquid–liquid equilibrium at 353.15 K. Based on the experimental and literature data, the possibilities that chemical equilibrium exists in a homogeneous or heterogeneous region of compositions has been analyzed. The temperature shift of chemical and phase equilibria and the values of the thermodynamic constants of chemical equilibrium are discussed.

AB - The paper presents new experimental data on the chemical equilibrium in the system n-propanol + acetic acid + n-propyl acetate + water at 293.15 and 353.15 K, and the data on liquid–liquid equilibrium at 353.15 K. Based on the experimental and literature data, the possibilities that chemical equilibrium exists in a homogeneous or heterogeneous region of compositions has been analyzed. The temperature shift of chemical and phase equilibria and the values of the thermodynamic constants of chemical equilibrium are discussed.

KW - chemical equilibrium

KW - equilibrium constant

KW - liquid–liquid equilibrium

KW - n-propyl acetate

KW - splitting

UR - http://www.scopus.com/inward/record.url?scp=84992665648&partnerID=8YFLogxK

U2 - 10.1134/S0040579516050377

DO - 10.1134/S0040579516050377

M3 - Article

VL - 50

SP - 739

EP - 745

JO - Theoretical Foundations of Chemical Engineering

JF - Theoretical Foundations of Chemical Engineering

SN - 0040-5795

IS - 5

ER -

ID: 92644340