Novel experimental values of collisional broadening and shifting coefficients for the Fermi triad of CO2 in mixture with methane at 296.0(2) K were determined from high resolution FTIR measurements. An empirical function for the broadening coefficients is obtained: γn(J′) = 0.0762(7) + 0.00320(4) · exp(− 0.039(3) · J′) /cm–1/atm, here J′ refers to the final state, n = 1, 2, 3 labels the Fermi components. Expanded uncertainties (2σ) for 38 out of 55 reported values are smaller than 0.5%. The absolute values of shift coefficients are about ten times smaller than the broadening, and the relative uncertainty is larger (4–5%).

Original languageEnglish
Pages (from-to)209-216
Number of pages8
JournalJournal of Quantitative Spectroscopy and Radiative Transfer
Volume235
DOIs
StatePublished - 1 Sep 2019

    Research areas

  • Carbon dioxide, Fermi triad, FTIR, Gas, Hydrocarbon, Infrared, Methane, Pressure broadening, Pressure shifting, CO2, AIR, PARAMETERS, BAND, WIDTHS, SEPARATION, CARBON-DIOXIDE

    Scopus subject areas

  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Spectroscopy

ID: 45845565