CdBiO2NO3, a new layered bismuth oxide nitrate

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CdBiO₂NO₃, a new layered bismuth oxide nitrate. / Charkin, D. O.; Plokhikh, I. V.; Zadoya, A. I.; Kuznetsova, P. L.; Kazakov, S. M.; Siidra, O. I.

In: Solid State Sciences, Vol. 84, 01.10.2018, p. 23-27.

Research output: Contribution to journal › Article › peer-review

Author

Charkin, D. O. ; Plokhikh, I. V. ; Zadoya, A. I. ; Kuznetsova, P. L. ; Kazakov, S. M. ; Siidra, O. I. / CdBiO₂NO₃, a new layered bismuth oxide nitrate. In: Solid State Sciences. 2018 ; Vol. 84. pp. 23-27.

BibTeX

@article{ff88f38d850c4c39a3ca3af97c599b96,

title = "CdBiO2NO3, a new layered bismuth oxide nitrate",

abstract = "Step-wise reaction of CdO, Bi2O3, and Cd(NO3)2 ·4H2O leads to formation of a novel bismuth oxide nitrate, CdBiO2NO3, which completes the family of bismuthite-like MIIBiO2NO3 oxide nitrates. The new compound is tetragonal, I4/mmm, a = 3.9486(1){\AA} c = 14.2235(2){\AA}; its crystal structure resembles those of PbBiO2NO3 and CaBiO2NO3, except for, probably, different positioning of the nitrate group. The compound is stable until ∼425 °C when it decomposes, in one step, into CdO and a mixture of Bi–Cd oxides. Cd-based analogs of isostructural PbLnO2NO3 (Ln – lanthanides) oxide nitrates are unlikely to exist. We discuss the similarities and differences in the structures of layered oxyhalides and oxynitrates of bismuth and rare-earths.",

keywords = "COMPOUND, CRYSTAL-STRUCTURES, FLUORIDE, LN, ND, PR, SM, THERMAL-DECOMPOSITION",

author = "Charkin, {D. O.} and Plokhikh, {I. V.} and Zadoya, {A. I.} and Kuznetsova, {P. L.} and Kazakov, {S. M.} and Siidra, {O. I.}",

year = "2018",

month = oct,

day = "1",

doi = "10.1016/j.solidstatesciences.2018.08.001",

language = "English",

volume = "84",

pages = "23--27",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - CdBiO2NO3, a new layered bismuth oxide nitrate

AU - Charkin, D. O.

AU - Plokhikh, I. V.

AU - Zadoya, A. I.

AU - Kuznetsova, P. L.

AU - Kazakov, S. M.

AU - Siidra, O. I.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - Step-wise reaction of CdO, Bi2O3, and Cd(NO3)2 ·4H2O leads to formation of a novel bismuth oxide nitrate, CdBiO2NO3, which completes the family of bismuthite-like MIIBiO2NO3 oxide nitrates. The new compound is tetragonal, I4/mmm, a = 3.9486(1)Å c = 14.2235(2)Å; its crystal structure resembles those of PbBiO2NO3 and CaBiO2NO3, except for, probably, different positioning of the nitrate group. The compound is stable until ∼425 °C when it decomposes, in one step, into CdO and a mixture of Bi–Cd oxides. Cd-based analogs of isostructural PbLnO2NO3 (Ln – lanthanides) oxide nitrates are unlikely to exist. We discuss the similarities and differences in the structures of layered oxyhalides and oxynitrates of bismuth and rare-earths.

AB - Step-wise reaction of CdO, Bi2O3, and Cd(NO3)2 ·4H2O leads to formation of a novel bismuth oxide nitrate, CdBiO2NO3, which completes the family of bismuthite-like MIIBiO2NO3 oxide nitrates. The new compound is tetragonal, I4/mmm, a = 3.9486(1)Å c = 14.2235(2)Å; its crystal structure resembles those of PbBiO2NO3 and CaBiO2NO3, except for, probably, different positioning of the nitrate group. The compound is stable until ∼425 °C when it decomposes, in one step, into CdO and a mixture of Bi–Cd oxides. Cd-based analogs of isostructural PbLnO2NO3 (Ln – lanthanides) oxide nitrates are unlikely to exist. We discuss the similarities and differences in the structures of layered oxyhalides and oxynitrates of bismuth and rare-earths.

KW - COMPOUND

KW - CRYSTAL-STRUCTURES

KW - FLUORIDE

KW - LN

KW - ND

KW - PR

KW - SM

KW - THERMAL-DECOMPOSITION

UR - http://www.scopus.com/inward/record.url?scp=85053187648&partnerID=8YFLogxK

U2 - 10.1016/j.solidstatesciences.2018.08.001

DO - 10.1016/j.solidstatesciences.2018.08.001

M3 - Article

AN - SCOPUS:85053187648

VL - 84

SP - 23

EP - 27

JO - Solid State Sciences

JF - Solid State Sciences

SN - 1293-2558

ER -

ID: 34508964