Research output: Contribution to journal › Article › peer-review
Catena-Poly[[cobalt(II)-μ-aqua-μ-propano-ato-κ2 O : O′ -μ-propano-ato-κ2 O:O] monohydrate]. / Fischer, A. I.; Gurzhiy, V. V.; Belyaev, A. N.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 11, 11.2010.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Catena-Poly[[cobalt(II)-μ-aqua-μ-propano-ato-κ2 O
T2 - O′ -μ-propano-ato-κ2 O:O] monohydrate]
AU - Fischer, A. I.
AU - Gurzhiy, V. V.
AU - Belyaev, A. N.
PY - 2010/11
Y1 - 2010/11
N2 - The title compound, {[Co(C2H5COO)2(H 2O)]·H2O} n, was synthesized by the reaction of cobalt(II) carbonate hydrate with aqueous propionic acid. The structure consists of polymeric infinite linear chains with composition [Co(C2H 5COO)4/2(H2O)2/2] running along [010]. The chains are formed by Co2+ ions linked with bridging propionate groups and water mol-ecules, with a Co⋯Co distance along the chains of 3.2587 (9) Å. The Co2+ ion is six-coordinated in a strongly distorted octa-hedral geometry. The chains are connected to each other by a network of O - H⋯O hydrogen bonds involving solvent water mol-ecules.
AB - The title compound, {[Co(C2H5COO)2(H 2O)]·H2O} n, was synthesized by the reaction of cobalt(II) carbonate hydrate with aqueous propionic acid. The structure consists of polymeric infinite linear chains with composition [Co(C2H 5COO)4/2(H2O)2/2] running along [010]. The chains are formed by Co2+ ions linked with bridging propionate groups and water mol-ecules, with a Co⋯Co distance along the chains of 3.2587 (9) Å. The Co2+ ion is six-coordinated in a strongly distorted octa-hedral geometry. The chains are connected to each other by a network of O - H⋯O hydrogen bonds involving solvent water mol-ecules.
UR - http://www.scopus.com/inward/record.url?scp=78650944167&partnerID=8YFLogxK
U2 - 10.1107/S1600536810043540
DO - 10.1107/S1600536810043540
M3 - Article
AN - SCOPUS:78650944167
VL - 66
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
SN - 2056-9890
IS - 11
ER -
ID: 9152107