Research output: Contribution to journal › Article › peer-review
Calculation of the association constants of polynucleotides in solutions. / Kudrev, A. G.
In: Polymer Science - Series A, Vol. 42, No. 5, 01.05.2000, p. 527-532.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Calculation of the association constants of polynucleotides in solutions
AU - Kudrev, A. G.
PY - 2000/5/1
Y1 - 2000/5/1
N2 - A mathematical analysis of the titration data for the ideal polymer containing a periodically repeating functional group capable of reversibly attaching ligands in solution was performed. The titration curves were described by applying a matrix method to calculate the equilibrium constant of polymer complex formation. The results of mathematical modeling were compared with experimental data. On this basis, the concentration dependence of the equilibrium constant for the deprotonation of a synthetic poly(ribouridylic acid) in aqueous solution was proposed.
AB - A mathematical analysis of the titration data for the ideal polymer containing a periodically repeating functional group capable of reversibly attaching ligands in solution was performed. The titration curves were described by applying a matrix method to calculate the equilibrium constant of polymer complex formation. The results of mathematical modeling were compared with experimental data. On this basis, the concentration dependence of the equilibrium constant for the deprotonation of a synthetic poly(ribouridylic acid) in aqueous solution was proposed.
UR - http://www.scopus.com/inward/record.url?scp=0034341170&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0034341170
VL - 42
SP - 527
EP - 532
JO - Polymer Science - Series A
JF - Polymer Science - Series A
SN - 0965-545X
IS - 5
ER -
ID: 47621693