Research output: Contribution to journal › Article › peer-review
Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers. / Rodygin, Konstantin S.; Kostin, Anton A.; Ananikov, Valentine P.
In: Mendeleev Communications , Vol. 25, No. 6, 01.11.2015, p. 415-416.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers
AU - Rodygin, Konstantin S.
AU - Kostin, Anton A.
AU - Ananikov, Valentine P.
N1 - Publisher Copyright: © 2015 Mendeleev Communications. Published by ELSEVIER B.V. on behalf of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences.
PY - 2015/11/1
Y1 - 2015/11/1
N2 - Calcium carbide was studied as a useful solid-state reagent to incorporate acetylene unit into synthetic procedures. Atom-economic thiol-yne click reaction was successfully performed with single and double additions. Heterocyclic thiols and aliphatic dithiols reacted with acetylene generated in situ from calcium carbide to afford corresponding vinyl sulfides and bis(thiovinyl)ethers in good to high yields.
AB - Calcium carbide was studied as a useful solid-state reagent to incorporate acetylene unit into synthetic procedures. Atom-economic thiol-yne click reaction was successfully performed with single and double additions. Heterocyclic thiols and aliphatic dithiols reacted with acetylene generated in situ from calcium carbide to afford corresponding vinyl sulfides and bis(thiovinyl)ethers in good to high yields.
UR - http://www.scopus.com/inward/record.url?scp=84951284731&partnerID=8YFLogxK
U2 - 10.1016/j.mencom.2015.11.004
DO - 10.1016/j.mencom.2015.11.004
M3 - Article
AN - SCOPUS:84951284731
VL - 25
SP - 415
EP - 416
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 6
ER -
ID: 100855145