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Bulky Polyfluorinated Terphenyldiphenylboranes : Water Tolerant Lewis Acids. / Stoian, Corina; Olaru, Marian; Cucuiet, Teodor A.; Kegyes, Krisztina T.; Sava, Alexandru; Timoshkin, Alexey Y.; Raţ, Ciprian I.; Beckmann, Jens.

In: Chemistry - A European Journal, Vol. 27, No. 13, 01.03.2021, p. 4327-4331.

Research output: Contribution to journal › Article › peer-review

Harvard

Stoian, C, Olaru, M, Cucuiet, TA, Kegyes, KT, Sava, A, Timoshkin, AY, Raţ, CI & Beckmann, J 2021, 'Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids', Chemistry - A European Journal, vol. 27, no. 13, pp. 4327-4331. https://doi.org/10.1002/chem.202005367

APA

Stoian, C., Olaru, M., Cucuiet, T. A., Kegyes, K. T., Sava, A., Timoshkin, A. Y., Raţ, C. I., & Beckmann, J. (2021). Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids. Chemistry - A European Journal, 27(13), 4327-4331. https://doi.org/10.1002/chem.202005367

Vancouver

Stoian C, Olaru M, Cucuiet TA, Kegyes KT, Sava A, Timoshkin AY et al. Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids. Chemistry - A European Journal. 2021 Mar 1;27(13):4327-4331. https://doi.org/10.1002/chem.202005367

Author

Stoian, Corina ; Olaru, Marian ; Cucuiet, Teodor A. ; Kegyes, Krisztina T. ; Sava, Alexandru ; Timoshkin, Alexey Y. ; Raţ, Ciprian I. ; Beckmann, Jens. / Bulky Polyfluorinated Terphenyldiphenylboranes : Water Tolerant Lewis Acids. In: Chemistry - A European Journal. 2021 ; Vol. 27, No. 13. pp. 4327-4331.

BibTeX

@article{b9f92add2559408986b9b511c2d31366,
title = "Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids",
abstract = "Protocols for the synthesis of the bulky polyfluorinated triarylboranes 2,6-(C6F5)2C6F3B(C6F5)2 (1), 2,6-(C6F5)2C6F3B[3,5-(CF3)2C6H3] (2), 2,4,6-(C6F5)3C6H2B(C6F5)2 (3), 2,4,6-(C6F5)3C6H2B[3,5-(CF3)2C6H3] (4) were developed. All boranes are water tolerant and according to the Gutmann-Beckett method, 1–3 display Lewis acidities larger than that of the prominent B(C6F5)3.",
keywords = "fluorinated compounds, kinetic stabilization, Lewis acids, terphenyl, water tolerant boranes",
author = "Corina Stoian and Marian Olaru and Cucuiet, {Teodor A.} and Kegyes, {Krisztina T.} and Alexandru Sava and Timoshkin, {Alexey Y.} and Ra{\c t}, {Ciprian I.} and Jens Beckmann",
note = "Funding Information: The Deutsche Forschungsgemeinschaft (DFG) and Romanian National Authority for Scientific Research and Innovation, CNCS‐UEFISCDI, project number PN‐II‐RU‐TE‐2014‐4‐0906, are gratefully acknowledged for financial support. C. S. acknowledges Erasmus+ for a training scholarship. Computational work was financially supported by the Russian Science Foundation (grant no. 18‐13‐00196 to A.Y.T.). Use of equipment of Resource center „Computing Center“ of the Scientific park of St. Petersburg State University is gratefully acknowledged. Open access funding enabled and organized by Projekt DEAL. Publisher Copyright: {\textcopyright} 2020 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = mar,
day = "1",
doi = "10.1002/chem.202005367",
language = "English",
volume = "27",
pages = "4327--4331",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-Blackwell",
number = "13",

}

RIS

TY - JOUR

T1 - Bulky Polyfluorinated Terphenyldiphenylboranes

T2 - Water Tolerant Lewis Acids

AU - Stoian, Corina

AU - Olaru, Marian

AU - Cucuiet, Teodor A.

AU - Kegyes, Krisztina T.

AU - Sava, Alexandru

AU - Timoshkin, Alexey Y.

AU - Raţ, Ciprian I.

AU - Beckmann, Jens

N1 - Funding Information: The Deutsche Forschungsgemeinschaft (DFG) and Romanian National Authority for Scientific Research and Innovation, CNCS‐UEFISCDI, project number PN‐II‐RU‐TE‐2014‐4‐0906, are gratefully acknowledged for financial support. C. S. acknowledges Erasmus+ for a training scholarship. Computational work was financially supported by the Russian Science Foundation (grant no. 18‐13‐00196 to A.Y.T.). Use of equipment of Resource center „Computing Center“ of the Scientific park of St. Petersburg State University is gratefully acknowledged. Open access funding enabled and organized by Projekt DEAL. Publisher Copyright: © 2020 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/3/1

Y1 - 2021/3/1

N2 - Protocols for the synthesis of the bulky polyfluorinated triarylboranes 2,6-(C6F5)2C6F3B(C6F5)2 (1), 2,6-(C6F5)2C6F3B[3,5-(CF3)2C6H3] (2), 2,4,6-(C6F5)3C6H2B(C6F5)2 (3), 2,4,6-(C6F5)3C6H2B[3,5-(CF3)2C6H3] (4) were developed. All boranes are water tolerant and according to the Gutmann-Beckett method, 1–3 display Lewis acidities larger than that of the prominent B(C6F5)3.

AB - Protocols for the synthesis of the bulky polyfluorinated triarylboranes 2,6-(C6F5)2C6F3B(C6F5)2 (1), 2,6-(C6F5)2C6F3B[3,5-(CF3)2C6H3] (2), 2,4,6-(C6F5)3C6H2B(C6F5)2 (3), 2,4,6-(C6F5)3C6H2B[3,5-(CF3)2C6H3] (4) were developed. All boranes are water tolerant and according to the Gutmann-Beckett method, 1–3 display Lewis acidities larger than that of the prominent B(C6F5)3.

KW - fluorinated compounds

KW - kinetic stabilization

KW - Lewis acids

KW - terphenyl

KW - water tolerant boranes

UR - http://www.scopus.com/inward/record.url?scp=85100213541&partnerID=8YFLogxK

U2 - 10.1002/chem.202005367

DO - 10.1002/chem.202005367

M3 - Article

AN - SCOPUS:85100213541

VL - 27

SP - 4327

EP - 4331

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 13

ER -

ID: 74538561