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Bromoantimonates with bis(pyridinium)-type dications obtained via oxidation by dibromine : Diverse structural types and features of interactions pattern. / Bondarenko, Mikhail A.; Abramov, Pavel A.; Plyusnin, Pavel E.; Novikov, Alexander S.; Sokolov, Maxim N.; Adonin, Sergey A.

In: Polyhedron, Vol. 202, 115217, 01.07.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Bondarenko, MA, Abramov, PA, Plyusnin, PE, Novikov, AS, Sokolov, MN & Adonin, SA 2021, 'Bromoantimonates with bis(pyridinium)-type dications obtained via oxidation by dibromine: Diverse structural types and features of interactions pattern', Polyhedron, vol. 202, 115217. https://doi.org/10.1016/j.poly.2021.115217

APA

Bondarenko, M. A., Abramov, P. A., Plyusnin, P. E., Novikov, A. S., Sokolov, M. N., & Adonin, S. A. (2021). Bromoantimonates with bis(pyridinium)-type dications obtained via oxidation by dibromine: Diverse structural types and features of interactions pattern. Polyhedron, 202, [115217]. https://doi.org/10.1016/j.poly.2021.115217

Vancouver

Bondarenko MA, Abramov PA, Plyusnin PE, Novikov AS, Sokolov MN, Adonin SA. Bromoantimonates with bis(pyridinium)-type dications obtained via oxidation by dibromine: Diverse structural types and features of interactions pattern. Polyhedron. 2021 Jul 1;202. 115217. https://doi.org/10.1016/j.poly.2021.115217

Author

Bondarenko, Mikhail A. ; Abramov, Pavel A. ; Plyusnin, Pavel E. ; Novikov, Alexander S. ; Sokolov, Maxim N. ; Adonin, Sergey A. / Bromoantimonates with bis(pyridinium)-type dications obtained via oxidation by dibromine : Diverse structural types and features of interactions pattern. In: Polyhedron. 2021 ; Vol. 202.

BibTeX

@article{ec75b9f8d31c4e4c9ff515ba24cdb43b,
title = "Bromoantimonates with bis(pyridinium)-type dications obtained via oxidation by dibromine: Diverse structural types and features of interactions pattern",
abstract = "Bromoantimonate(III) species, which can be generated in solution by reaction of Sb2O3 and HBr, can be oxidized by Br2 into mixed-valence complexes or bromoantimonates(V). The outcome of these reactions governs by the nature of cation which salt is used for isolation of solid complexes. Using bromides of three 1,n-bis(pyridinium)alkane cations (PyCn, where X = 2, 3 and 4), we isolated three complexes: (PyC2){[SbBr6](Br3)} (1), (PyC3)2[Sb2Br9][SbBr6] (2) and (PyC4){[SbBr6](Br3)} (3), respectively. Their structures were determined by X-ray diffractometry. For 1 and 3, the energies of non-covalent interactions between tribromide units and [SbBr6]− were estimated using DFT calculations.",
keywords = "Antimony, Crystal structure, Halide complexes, Non-covalent interactions, Polybromides, VAN, METHYLAMMONIUM LEAD, CRYSTAL-STRUCTURE, IODIDE, RADII, PEROVSKITE, HALOGEN BOND",
author = "Bondarenko, {Mikhail A.} and Abramov, {Pavel A.} and Plyusnin, {Pavel E.} and Novikov, {Alexander S.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",
note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = jul,
day = "1",
doi = "10.1016/j.poly.2021.115217",
language = "English",
volume = "202",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Bromoantimonates with bis(pyridinium)-type dications obtained via oxidation by dibromine

T2 - Diverse structural types and features of interactions pattern

AU - Bondarenko, Mikhail A.

AU - Abramov, Pavel A.

AU - Plyusnin, Pavel E.

AU - Novikov, Alexander S.

AU - Sokolov, Maxim N.

AU - Adonin, Sergey A.

N1 - Publisher Copyright: © 2021 Elsevier Ltd Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/7/1

Y1 - 2021/7/1

N2 - Bromoantimonate(III) species, which can be generated in solution by reaction of Sb2O3 and HBr, can be oxidized by Br2 into mixed-valence complexes or bromoantimonates(V). The outcome of these reactions governs by the nature of cation which salt is used for isolation of solid complexes. Using bromides of three 1,n-bis(pyridinium)alkane cations (PyCn, where X = 2, 3 and 4), we isolated three complexes: (PyC2){[SbBr6](Br3)} (1), (PyC3)2[Sb2Br9][SbBr6] (2) and (PyC4){[SbBr6](Br3)} (3), respectively. Their structures were determined by X-ray diffractometry. For 1 and 3, the energies of non-covalent interactions between tribromide units and [SbBr6]− were estimated using DFT calculations.

AB - Bromoantimonate(III) species, which can be generated in solution by reaction of Sb2O3 and HBr, can be oxidized by Br2 into mixed-valence complexes or bromoantimonates(V). The outcome of these reactions governs by the nature of cation which salt is used for isolation of solid complexes. Using bromides of three 1,n-bis(pyridinium)alkane cations (PyCn, where X = 2, 3 and 4), we isolated three complexes: (PyC2){[SbBr6](Br3)} (1), (PyC3)2[Sb2Br9][SbBr6] (2) and (PyC4){[SbBr6](Br3)} (3), respectively. Their structures were determined by X-ray diffractometry. For 1 and 3, the energies of non-covalent interactions between tribromide units and [SbBr6]− were estimated using DFT calculations.

KW - Antimony

KW - Crystal structure

KW - Halide complexes

KW - Non-covalent interactions

KW - Polybromides

KW - VAN

KW - METHYLAMMONIUM LEAD

KW - CRYSTAL-STRUCTURE

KW - IODIDE

KW - RADII

KW - PEROVSKITE

KW - HALOGEN BOND

UR - http://www.scopus.com/inward/record.url?scp=85105312260&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2021.115217

DO - 10.1016/j.poly.2021.115217

M3 - Article

AN - SCOPUS:85105312260

VL - 202

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 115217

ER -

ID: 77245376