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Bromine-rich tin(IV) halide complexes : Experimental and theoretical examination of Br···Br noncovalent interactions in crystalline state. / Korobeynikov, Nikita A.; Usoltsev, Andrey N.; Abramov, Pavel A.; Novikov, Alexander S.; Sokolov, Maxim N.; Adonin, Sergey A.

In: Polyhedron, Vol. 222, 115912, 01.08.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Korobeynikov, NA, Usoltsev, AN, Abramov, PA, Novikov, AS, Sokolov, MN & Adonin, SA 2022, 'Bromine-rich tin(IV) halide complexes: Experimental and theoretical examination of Br···Br noncovalent interactions in crystalline state', Polyhedron, vol. 222, 115912. https://doi.org/10.1016/j.poly.2022.115912

APA

Korobeynikov, N. A., Usoltsev, A. N., Abramov, P. A., Novikov, A. S., Sokolov, M. N., & Adonin, S. A. (2022). Bromine-rich tin(IV) halide complexes: Experimental and theoretical examination of Br···Br noncovalent interactions in crystalline state. Polyhedron, 222, [115912]. https://doi.org/10.1016/j.poly.2022.115912

Vancouver

Korobeynikov NA, Usoltsev AN, Abramov PA, Novikov AS, Sokolov MN, Adonin SA. Bromine-rich tin(IV) halide complexes: Experimental and theoretical examination of Br···Br noncovalent interactions in crystalline state. Polyhedron. 2022 Aug 1;222. 115912. https://doi.org/10.1016/j.poly.2022.115912

Author

Korobeynikov, Nikita A. ; Usoltsev, Andrey N. ; Abramov, Pavel A. ; Novikov, Alexander S. ; Sokolov, Maxim N. ; Adonin, Sergey A. / Bromine-rich tin(IV) halide complexes : Experimental and theoretical examination of Br···Br noncovalent interactions in crystalline state. In: Polyhedron. 2022 ; Vol. 222.

BibTeX

@article{1ed4d2f6e29441e3b1da17781b70928f,
title = "Bromine-rich tin(IV) halide complexes: Experimental and theoretical examination of Br···Br noncovalent interactions in crystalline state",
abstract = "Reactions between SnBr2, HBr, Br2 and bromides of different organic cations yields in formation of supramolecular bromostannate(IV) complexes where polybromide fragments are “trapped” in solid state by Br···Br noncovalent interactions. Five compounds of this family – Cat2{[SnBr6](Br2)} (cat = Me4N+ (1), 1-MePy+ (2), Me3NH+ (3), 2-MePyH+ (4)) and (4-MePyH)3{[SnBr6](Br5)} (5) – were prepared and characterized by X-ray diffractometry and Raman spectroscopy. Using DFT calculations and QTAIM analysis, we prove the existence of Br···Br noncovalent interactions in the obtained X-ray structures.",
keywords = "Bromine, Halide complexes, Halogen bonding, Non-covalent interactions, Polyhalogens, Tin",
author = "Korobeynikov, {Nikita A.} and Usoltsev, {Andrey N.} and Abramov, {Pavel A.} and Novikov, {Alexander S.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",
note = "Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",
year = "2022",
month = aug,
day = "1",
doi = "10.1016/j.poly.2022.115912",
language = "English",
volume = "222",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Bromine-rich tin(IV) halide complexes

T2 - Experimental and theoretical examination of Br···Br noncovalent interactions in crystalline state

AU - Korobeynikov, Nikita A.

AU - Usoltsev, Andrey N.

AU - Abramov, Pavel A.

AU - Novikov, Alexander S.

AU - Sokolov, Maxim N.

AU - Adonin, Sergey A.

N1 - Publisher Copyright: © 2022 Elsevier Ltd

PY - 2022/8/1

Y1 - 2022/8/1

N2 - Reactions between SnBr2, HBr, Br2 and bromides of different organic cations yields in formation of supramolecular bromostannate(IV) complexes where polybromide fragments are “trapped” in solid state by Br···Br noncovalent interactions. Five compounds of this family – Cat2{[SnBr6](Br2)} (cat = Me4N+ (1), 1-MePy+ (2), Me3NH+ (3), 2-MePyH+ (4)) and (4-MePyH)3{[SnBr6](Br5)} (5) – were prepared and characterized by X-ray diffractometry and Raman spectroscopy. Using DFT calculations and QTAIM analysis, we prove the existence of Br···Br noncovalent interactions in the obtained X-ray structures.

AB - Reactions between SnBr2, HBr, Br2 and bromides of different organic cations yields in formation of supramolecular bromostannate(IV) complexes where polybromide fragments are “trapped” in solid state by Br···Br noncovalent interactions. Five compounds of this family – Cat2{[SnBr6](Br2)} (cat = Me4N+ (1), 1-MePy+ (2), Me3NH+ (3), 2-MePyH+ (4)) and (4-MePyH)3{[SnBr6](Br5)} (5) – were prepared and characterized by X-ray diffractometry and Raman spectroscopy. Using DFT calculations and QTAIM analysis, we prove the existence of Br···Br noncovalent interactions in the obtained X-ray structures.

KW - Bromine

KW - Halide complexes

KW - Halogen bonding

KW - Non-covalent interactions

KW - Polyhalogens

KW - Tin

UR - http://www.scopus.com/inward/record.url?scp=85130334481&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/1c74f2ba-ef1b-3050-9ba2-55eea4b4ab2e/

U2 - 10.1016/j.poly.2022.115912

DO - 10.1016/j.poly.2022.115912

M3 - Article

AN - SCOPUS:85130334481

VL - 222

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 115912

ER -

ID: 95739806