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Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag4B4O7X2 (X = Br, I) Borate Halides. / Volkov, Sergey N.; Charkin, Dmitri O.; Arsent'Ev, Maxim Yu; Povolotskiy, Alexey V.; Stefanovich, Sergey Yu; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Shilovskikh, Vladimir V.; Bubnova, Rimma S.

In: Inorganic Chemistry, Vol. 59, No. 5, 02.03.2020, p. 2655-2658.

Research output: Contribution to journal › Article › peer-review

Harvard

Volkov, SN, Charkin, DO, Arsent'Ev, MY, Povolotskiy, AV, Stefanovich, SY, Ugolkov, VL, Krzhizhanovskaya, MG, Shilovskikh, VV & Bubnova, RS 2020, 'Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag4B4O7X2 (X = Br, I) Borate Halides', Inorganic Chemistry, vol. 59, no. 5, pp. 2655-2658. https://doi.org/10.1021/acs.inorgchem.0c00306

APA

Volkov, S. N., Charkin, D. O., Arsent'Ev, M. Y., Povolotskiy, A. V., Stefanovich, S. Y., Ugolkov, V. L., Krzhizhanovskaya, M. G., Shilovskikh, V. V., & Bubnova, R. S. (2020). Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag4B4O7X2 (X = Br, I) Borate Halides. Inorganic Chemistry, 59(5), 2655-2658. https://doi.org/10.1021/acs.inorgchem.0c00306

Vancouver

Volkov SN, Charkin DO, Arsent'Ev MY, Povolotskiy AV, Stefanovich SY, Ugolkov VL et al. Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag4B4O7X2 (X = Br, I) Borate Halides. Inorganic Chemistry. 2020 Mar 2;59(5):2655-2658. https://doi.org/10.1021/acs.inorgchem.0c00306

Author

Volkov, Sergey N. ; Charkin, Dmitri O. ; Arsent'Ev, Maxim Yu ; Povolotskiy, Alexey V. ; Stefanovich, Sergey Yu ; Ugolkov, Valery L. ; Krzhizhanovskaya, Maria G. ; Shilovskikh, Vladimir V. ; Bubnova, Rimma S. / Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag4B4O7X2 (X = Br, I) Borate Halides. In: Inorganic Chemistry. 2020 ; Vol. 59, No. 5. pp. 2655-2658.

BibTeX

@article{2d78e655782846f8b6f080544de8202d,
title = "Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag4B4O7X2 (X = Br, I) Borate Halides",
abstract = "An acentric borate family, Ag4B4O7X2 (X = Br, I), has been prepared by slow cooling stoichiometric melts in evacuated silica ampules. Their crystal structure is comprised of two porous interpenetrating frameworks and demonstrates a further development of the {"}salt-inclusion{"} architecture toward a {"}covalent-inclusion{"} structure. The (Ag2X)+ sublattice shows strong anharmonic vibrations. Thermal expansion is strongly anisotropic because of the presence of condensed rigid kernite boron-oxygen chains aligned perpendicular to the c axes.",
author = "Volkov, {Sergey N.} and Charkin, {Dmitri O.} and Arsent'Ev, {Maxim Yu} and Povolotskiy, {Alexey V.} and Stefanovich, {Sergey Yu} and Ugolkov, {Valery L.} and Krzhizhanovskaya, {Maria G.} and Shilovskikh, {Vladimir V.} and Bubnova, {Rimma S.}",
year = "2020",
month = mar,
day = "2",
doi = "10.1021/acs.inorgchem.0c00306",
language = "English",
volume = "59",
pages = "2655--2658",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "5",

}

RIS

TY - JOUR

T1 - Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag4B4O7X2 (X = Br, I) Borate Halides

AU - Volkov, Sergey N.

AU - Charkin, Dmitri O.

AU - Arsent'Ev, Maxim Yu

AU - Povolotskiy, Alexey V.

AU - Stefanovich, Sergey Yu

AU - Ugolkov, Valery L.

AU - Krzhizhanovskaya, Maria G.

AU - Shilovskikh, Vladimir V.

AU - Bubnova, Rimma S.

PY - 2020/3/2

Y1 - 2020/3/2

N2 - An acentric borate family, Ag4B4O7X2 (X = Br, I), has been prepared by slow cooling stoichiometric melts in evacuated silica ampules. Their crystal structure is comprised of two porous interpenetrating frameworks and demonstrates a further development of the "salt-inclusion" architecture toward a "covalent-inclusion" structure. The (Ag2X)+ sublattice shows strong anharmonic vibrations. Thermal expansion is strongly anisotropic because of the presence of condensed rigid kernite boron-oxygen chains aligned perpendicular to the c axes.

AB - An acentric borate family, Ag4B4O7X2 (X = Br, I), has been prepared by slow cooling stoichiometric melts in evacuated silica ampules. Their crystal structure is comprised of two porous interpenetrating frameworks and demonstrates a further development of the "salt-inclusion" architecture toward a "covalent-inclusion" structure. The (Ag2X)+ sublattice shows strong anharmonic vibrations. Thermal expansion is strongly anisotropic because of the presence of condensed rigid kernite boron-oxygen chains aligned perpendicular to the c axes.

UR - http://www.scopus.com/inward/record.url?scp=85079807428&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.0c00306

DO - 10.1021/acs.inorgchem.0c00306

M3 - Article

C2 - 32049501

AN - SCOPUS:85079807428

VL - 59

SP - 2655

EP - 2658

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 5

ER -

ID: 52382761