Research output: Contribution to journal › Article › peer-review
Bola-type PEG-linked polyaromatic hydrocarbon-based chemosensors for the “turn-off” excimer fluorescence detection of nitro-analytes/explosives in aqueous solutions. / Sadieva, Leila K.; Kovalev, Igor S.; Taniya, Olga S.; Platonov, Vadim A.; Novikov, Alexander S.; Berseneva, Vera S.; Santra, Sougata; Zyryanov, Grigory V.; Ranu, Brindaban C.; Charushin, Valery N.
In: Dyes and Pigments, Vol. 210, 01.02.2023, p. 111014.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Bola-type PEG-linked polyaromatic hydrocarbon-based chemosensors for the “turn-off” excimer fluorescence detection of nitro-analytes/explosives in aqueous solutions
AU - Sadieva, Leila K.
AU - Kovalev, Igor S.
AU - Taniya, Olga S.
AU - Platonov, Vadim A.
AU - Novikov, Alexander S.
AU - Berseneva, Vera S.
AU - Santra, Sougata
AU - Zyryanov, Grigory V.
AU - Ranu, Brindaban C.
AU - Charushin, Valery N.
PY - 2023/2/1
Y1 - 2023/2/1
N2 - Diesters of 1-pyrenecarboxylic acid with tri- and tetra - ethylene glycols were prepared and characterized for the first time and their photophysical and sensory properties were investigated. In aqueous solutions these compounds exhibited an intensive excimeric emission at 521 nm, which is attributed to the aggregation-induced fluorescence of the dimers, pre-associated in the ground state. In aqueous solutions an intensive “turn-off” fluorescence response towards common nitro-explosive components, such as 2,4-dinitrotoluene (2,4-DNT), 2,4,6-trinitrotoluene (TNT), as well as aliphatic nitro compounds, such as pentaerythritol tetranitrate (PETN), 1,3,5-trinitro-1,3,5-triazinane (RDX) and 2,3-dimethyl-2,3-dinitrobutane (DMDNB) was observed via the excimeric emission quenching. For the most representative chemosensor 4a the highest Stern-Volmer fluorescence quenching constant of 8.75 × 106 M−1 was observed in the presence of TNT.
AB - Diesters of 1-pyrenecarboxylic acid with tri- and tetra - ethylene glycols were prepared and characterized for the first time and their photophysical and sensory properties were investigated. In aqueous solutions these compounds exhibited an intensive excimeric emission at 521 nm, which is attributed to the aggregation-induced fluorescence of the dimers, pre-associated in the ground state. In aqueous solutions an intensive “turn-off” fluorescence response towards common nitro-explosive components, such as 2,4-dinitrotoluene (2,4-DNT), 2,4,6-trinitrotoluene (TNT), as well as aliphatic nitro compounds, such as pentaerythritol tetranitrate (PETN), 1,3,5-trinitro-1,3,5-triazinane (RDX) and 2,3-dimethyl-2,3-dinitrobutane (DMDNB) was observed via the excimeric emission quenching. For the most representative chemosensor 4a the highest Stern-Volmer fluorescence quenching constant of 8.75 × 106 M−1 was observed in the presence of TNT.
KW - Pyrene
KW - Bola-type chemosensor
KW - Photophysical studies
KW - Detection of explosives
KW - fluorescence quenching
KW - Detection in aqueous solutions
U2 - 10.1016/j.dyepig.2022.111014
DO - 10.1016/j.dyepig.2022.111014
M3 - Article
VL - 210
SP - 111014
JO - Dyes and Pigments
JF - Dyes and Pigments
SN - 0143-7208
ER -
ID: 103129359