Research output: Contribution to journal › Article › peer-review
Base-mediated intramolecular aryl–aryl coupling in pyrazolyl-containing iodolium salts. / Сафинская, Яна Валерьевна; Ильин, Михаил Вячеславович; Болотин, Дмитрий Сергеевич.
In: New Journal of Chemistry, 04.11.2024.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Base-mediated intramolecular aryl–aryl coupling in pyrazolyl-containing iodolium salts
AU - Сафинская, Яна Валерьевна
AU - Ильин, Михаил Вячеславович
AU - Болотин, Дмитрий Сергеевич
PY - 2024/11/4
Y1 - 2024/11/4
N2 - Pyrazolyl-containing aryliodolium salts undergo transformation to iodopyrazoles accompanied by the formation of a new Csp2-Csp2 bond in the presence of a base (DIPEA, NaOH, or K2CO3). The plausible mechanism of the base-mediated reaction is suggested. The catalytic activity of the iodine-containing species is studied in the model reaction.
AB - Pyrazolyl-containing aryliodolium salts undergo transformation to iodopyrazoles accompanied by the formation of a new Csp2-Csp2 bond in the presence of a base (DIPEA, NaOH, or K2CO3). The plausible mechanism of the base-mediated reaction is suggested. The catalytic activity of the iodine-containing species is studied in the model reaction.
UR - https://www.mendeley.com/catalogue/ea5275f0-d241-3538-8335-1f961aa7dc8e/
U2 - 10.1039/d4nj02894e
DO - 10.1039/d4nj02894e
M3 - Article
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
ER -
ID: 126741429