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Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex. / Grudova, Mariya V.; Novikov, Alexander S.; Kubasov, Alexey S.; Khrustalev, Victor N.; Kirichuk, Anatoly A.; Nenajdenko, Valentine G.; Tskhovrebov, Alexander G.

In: Crystals, Vol. 12, No. 5, 613, 26.04.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Grudova, MV, Novikov, AS, Kubasov, AS, Khrustalev, VN, Kirichuk, AA, Nenajdenko, VG & Tskhovrebov, AG 2022, 'Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex', Crystals, vol. 12, no. 5, 613. https://doi.org/10.3390/cryst12050613

APA

Grudova, M. V., Novikov, A. S., Kubasov, A. S., Khrustalev, V. N., Kirichuk, A. A., Nenajdenko, V. G., & Tskhovrebov, A. G. (2022). Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex. Crystals, 12(5), [613]. https://doi.org/10.3390/cryst12050613

Vancouver

Grudova MV, Novikov AS, Kubasov AS, Khrustalev VN, Kirichuk AA, Nenajdenko VG et al. Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex. Crystals. 2022 Apr 26;12(5). 613. https://doi.org/10.3390/cryst12050613

Author

Grudova, Mariya V. ; Novikov, Alexander S. ; Kubasov, Alexey S. ; Khrustalev, Victor N. ; Kirichuk, Anatoly A. ; Nenajdenko, Valentine G. ; Tskhovrebov, Alexander G. / Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex. In: Crystals. 2022 ; Vol. 12, No. 5.

BibTeX

@article{dca6479a66014f79a0733eeca8984dee,
title = "Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex",
abstract = "Gold(I) isocyanide complexes featuring Au---Au interactions attract considerable attention because of their tunable photophysical properties. Although the synthetic exploration of isocyanide gold(I) complexes seems reasonable, their structural diversity is mainly limited to linear gold(I) derivatives. The synthesis and structural characterization of cationic three-coordinate gold(I) mixed 22-bipyridyl/isocyanide complex are presented here for the first time. Cationic gold species form supramolecular dimers in the solid state via attractive Au---Au interactions. The nature and energies of aurophilic contacts, which are responsible for dimerization in the solid state, were studied by DFT calculations together with QTAIM, ELF, RDG, and NCI techniques and Hirshfeld surface analysis. The estimated energy of the aurophilic interactions was 6.3 kcal/mol.",
keywords = "aurophilic interactions, gold, isocyanides, noncovalent interactions",
author = "Grudova, {Mariya V.} and Novikov, {Alexander S.} and Kubasov, {Alexey S.} and Khrustalev, {Victor N.} and Kirichuk, {Anatoly A.} and Nenajdenko, {Valentine G.} and Tskhovrebov, {Alexander G.}",
note = "Grudova, M.V.; Novikov, A.S.; Kubasov, A.S.; Khrustalev, V.N.; Kirichuk, A.A.; Nenajdenko, V.G.; Tskhovrebov, A.G. Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex. Crystals 2022, 12, 613. https://doi.org/10.3390/cryst12050613",
year = "2022",
month = apr,
day = "26",
doi = "10.3390/cryst12050613",
language = "English",
volume = "12",
journal = "Crystals",
issn = "2073-4352",
publisher = "MDPI AG",
number = "5",

}

RIS

TY - JOUR

T1 - Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex

AU - Grudova, Mariya V.

AU - Novikov, Alexander S.

AU - Kubasov, Alexey S.

AU - Khrustalev, Victor N.

AU - Kirichuk, Anatoly A.

AU - Nenajdenko, Valentine G.

AU - Tskhovrebov, Alexander G.

N1 - Grudova, M.V.; Novikov, A.S.; Kubasov, A.S.; Khrustalev, V.N.; Kirichuk, A.A.; Nenajdenko, V.G.; Tskhovrebov, A.G. Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex. Crystals 2022, 12, 613. https://doi.org/10.3390/cryst12050613

PY - 2022/4/26

Y1 - 2022/4/26

N2 - Gold(I) isocyanide complexes featuring Au---Au interactions attract considerable attention because of their tunable photophysical properties. Although the synthetic exploration of isocyanide gold(I) complexes seems reasonable, their structural diversity is mainly limited to linear gold(I) derivatives. The synthesis and structural characterization of cationic three-coordinate gold(I) mixed 22-bipyridyl/isocyanide complex are presented here for the first time. Cationic gold species form supramolecular dimers in the solid state via attractive Au---Au interactions. The nature and energies of aurophilic contacts, which are responsible for dimerization in the solid state, were studied by DFT calculations together with QTAIM, ELF, RDG, and NCI techniques and Hirshfeld surface analysis. The estimated energy of the aurophilic interactions was 6.3 kcal/mol.

AB - Gold(I) isocyanide complexes featuring Au---Au interactions attract considerable attention because of their tunable photophysical properties. Although the synthetic exploration of isocyanide gold(I) complexes seems reasonable, their structural diversity is mainly limited to linear gold(I) derivatives. The synthesis and structural characterization of cationic three-coordinate gold(I) mixed 22-bipyridyl/isocyanide complex are presented here for the first time. Cationic gold species form supramolecular dimers in the solid state via attractive Au---Au interactions. The nature and energies of aurophilic contacts, which are responsible for dimerization in the solid state, were studied by DFT calculations together with QTAIM, ELF, RDG, and NCI techniques and Hirshfeld surface analysis. The estimated energy of the aurophilic interactions was 6.3 kcal/mol.

KW - aurophilic interactions

KW - gold

KW - isocyanides

KW - noncovalent interactions

UR - http://www.scopus.com/inward/record.url?scp=85130584135&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/47254472-5bba-3ac2-a507-613d4efbbce9/

U2 - 10.3390/cryst12050613

DO - 10.3390/cryst12050613

M3 - Article

AN - SCOPUS:85130584135

VL - 12

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 5

M1 - 613

ER -

ID: 95739690