Standard

Attractive fluorine···fluorine interactions between perfluorinated alkyl chains : A case of perfluorinated Cu(II) diiminate Cu[C2F5-C(NH)-CF=C(NH)-CF3]2. / Khrustalev, Victor N.; Savchenko, Anna O.; Zhukova, Anna I.; Chernikova, Natalia Yu; Kurykin, Michael A.; Novikov, Alexander S.; Tskhovrebov, Alexander G.

In: Zeitschrift fur Kristallographie - Crystalline Materials, Vol. 236, No. 3-4, 26.03.2021, p. 117-122.

Research output: Contribution to journal › Article › peer-review

Harvard

Khrustalev, VN, Savchenko, AO, Zhukova, AI, Chernikova, NY, Kurykin, MA, Novikov, AS & Tskhovrebov, AG 2021, 'Attractive fluorine···fluorine interactions between perfluorinated alkyl chains: A case of perfluorinated Cu(II) diiminate Cu[C2F5-C(NH)-CF=C(NH)-CF3]2', Zeitschrift fur Kristallographie - Crystalline Materials, vol. 236, no. 3-4, pp. 117-122. https://doi.org/10.1515/zkri-2021-2009

APA

Khrustalev, V. N., Savchenko, A. O., Zhukova, A. I., Chernikova, N. Y., Kurykin, M. A., Novikov, A. S., & Tskhovrebov, A. G. (2021). Attractive fluorine···fluorine interactions between perfluorinated alkyl chains: A case of perfluorinated Cu(II) diiminate Cu[C2F5-C(NH)-CF=C(NH)-CF3]2. Zeitschrift fur Kristallographie - Crystalline Materials, 236(3-4), 117-122. https://doi.org/10.1515/zkri-2021-2009

Vancouver

Khrustalev VN, Savchenko AO, Zhukova AI, Chernikova NY, Kurykin MA, Novikov AS et al. Attractive fluorine···fluorine interactions between perfluorinated alkyl chains: A case of perfluorinated Cu(II) diiminate Cu[C2F5-C(NH)-CF=C(NH)-CF3]2. Zeitschrift fur Kristallographie - Crystalline Materials. 2021 Mar 26;236(3-4):117-122. https://doi.org/10.1515/zkri-2021-2009

Author

Khrustalev, Victor N. ; Savchenko, Anna O. ; Zhukova, Anna I. ; Chernikova, Natalia Yu ; Kurykin, Michael A. ; Novikov, Alexander S. ; Tskhovrebov, Alexander G. / Attractive fluorine···fluorine interactions between perfluorinated alkyl chains : A case of perfluorinated Cu(II) diiminate Cu[C2F5-C(NH)-CF=C(NH)-CF3]2. In: Zeitschrift fur Kristallographie - Crystalline Materials. 2021 ; Vol. 236, No. 3-4. pp. 117-122.

BibTeX

@article{2fe2f58d63684d0f8a8271f9d24a0d34,
title = "Attractive fluorine···fluorine interactions between perfluorinated alkyl chains: A case of perfluorinated Cu(II) diiminate Cu[C2F5-C(NH)-CF=C(NH)-CF3]2",
abstract = "A synthesis of the perfluorinated copper diiminate complex Cu[C2F5-C(NH)-CF=C(NH)-CF3]2 (3) and its self-assembly into infinite 1D chains in the crystal via Type II C(sp3)-F···F-C(sp3) contacts between perfluoroethyl substituents is reported. Rare Type II F···F interactions were studied by DFT calculations and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method). This is the first report which discusses Type II contacts between perfuoroalkyl chains.",
keywords = "copper(II), DFT calculations, fluorine-fluorine interactions, non-covalent interactions, perfluorinated diiminates, X-ray diffraction",
author = "Khrustalev, {Victor N.} and Savchenko, {Anna O.} and Zhukova, {Anna I.} and Chernikova, {Natalia Yu} and Kurykin, {Michael A.} and Novikov, {Alexander S.} and Tskhovrebov, {Alexander G.}",
note = "Publisher Copyright: {\textcopyright} 2021 Walter de Gruyter GmbH, Berlin/Boston 2021. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = mar,
day = "26",
doi = "10.1515/zkri-2021-2009",
language = "English",
volume = "236",
pages = "117--122",
journal = "Zeitschrift fur Kristallographie - Crystalline Materials",
issn = "2194-4946",
publisher = "De Gruyter",
number = "3-4",

}

RIS

TY - JOUR

T1 - Attractive fluorine···fluorine interactions between perfluorinated alkyl chains

T2 - A case of perfluorinated Cu(II) diiminate Cu[C2F5-C(NH)-CF=C(NH)-CF3]2

AU - Khrustalev, Victor N.

AU - Savchenko, Anna O.

AU - Zhukova, Anna I.

AU - Chernikova, Natalia Yu

AU - Kurykin, Michael A.

AU - Novikov, Alexander S.

AU - Tskhovrebov, Alexander G.

N1 - Publisher Copyright: © 2021 Walter de Gruyter GmbH, Berlin/Boston 2021. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/3/26

Y1 - 2021/3/26

N2 - A synthesis of the perfluorinated copper diiminate complex Cu[C2F5-C(NH)-CF=C(NH)-CF3]2 (3) and its self-assembly into infinite 1D chains in the crystal via Type II C(sp3)-F···F-C(sp3) contacts between perfluoroethyl substituents is reported. Rare Type II F···F interactions were studied by DFT calculations and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method). This is the first report which discusses Type II contacts between perfuoroalkyl chains.

AB - A synthesis of the perfluorinated copper diiminate complex Cu[C2F5-C(NH)-CF=C(NH)-CF3]2 (3) and its self-assembly into infinite 1D chains in the crystal via Type II C(sp3)-F···F-C(sp3) contacts between perfluoroethyl substituents is reported. Rare Type II F···F interactions were studied by DFT calculations and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method). This is the first report which discusses Type II contacts between perfuoroalkyl chains.

KW - copper(II)

KW - DFT calculations

KW - fluorine-fluorine interactions

KW - non-covalent interactions

KW - perfluorinated diiminates

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85103623575&partnerID=8YFLogxK

U2 - 10.1515/zkri-2021-2009

DO - 10.1515/zkri-2021-2009

M3 - Article

AN - SCOPUS:85103623575

VL - 236

SP - 117

EP - 122

JO - Zeitschrift fur Kristallographie - Crystalline Materials

JF - Zeitschrift fur Kristallographie - Crystalline Materials

SN - 2194-4946

IS - 3-4

ER -

ID: 77245951