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Atom-economic synthesis of β-ketosulfones based on gold-catalyzed highly regioselective hydration of alkynylsulfones. / Chikunova, Elena I. ; Kukushkin, Vadim Yu. ; Dubovtsev, Alexey Yu. .

In: Green Chemistry, No. 24, 2022, p. 3314-3320.

Research output: Contribution to journal › Article › peer-review

Harvard

Chikunova, EI, Kukushkin, VY & Dubovtsev, AY 2022, 'Atom-economic synthesis of β-ketosulfones based on gold-catalyzed highly regioselective hydration of alkynylsulfones', Green Chemistry, no. 24, pp. 3314-3320.

APA

Chikunova, E. I., Kukushkin, V. Y., & Dubovtsev, A. Y. (2022). Atom-economic synthesis of β-ketosulfones based on gold-catalyzed highly regioselective hydration of alkynylsulfones. Green Chemistry, (24), 3314-3320.

Vancouver

Chikunova EI, Kukushkin VY, Dubovtsev AY. Atom-economic synthesis of β-ketosulfones based on gold-catalyzed highly regioselective hydration of alkynylsulfones. Green Chemistry. 2022;(24):3314-3320.

Author

Chikunova, Elena I. ; Kukushkin, Vadim Yu. ; Dubovtsev, Alexey Yu. . / Atom-economic synthesis of β-ketosulfones based on gold-catalyzed highly regioselective hydration of alkynylsulfones. In: Green Chemistry. 2022 ; No. 24. pp. 3314-3320.

BibTeX

@article{74476981d2d9480897645baa6b91854d,
title = "Atom-economic synthesis of β-ketosulfones based on gold-catalyzed highly regioselective hydration of alkynylsulfones",
abstract = "Gold(I)-catalyzed highly regioselective hydration of alkynylsulfones comprises an efficient 100% atom-economic route to β-ketosulfones. The reaction proceeds under mild mercury-free conditions (Ph3PAuNTf2 0.5–5 mol%, THF, rt or 60 °C), it demonstrates a high functional group tolerance (more than 30 examples; yields up to 99%), and can be easily scaled up. The developed hydration methodology was successfully integrated into the one-pot syntheses of valuable heterocycles.",
author = "Chikunova, {Elena I.} and Kukushkin, {Vadim Yu.} and Dubovtsev, {Alexey Yu.}",
year = "2022",
language = "English",
pages = "3314--3320",
journal = "Green Chemistry",
issn = "1463-9262",
publisher = "Royal Society of Chemistry",
number = "24",

}

RIS

TY - JOUR

T1 - Atom-economic synthesis of β-ketosulfones based on gold-catalyzed highly regioselective hydration of alkynylsulfones

AU - Chikunova, Elena I.

AU - Kukushkin, Vadim Yu.

AU - Dubovtsev, Alexey Yu.

PY - 2022

Y1 - 2022

N2 - Gold(I)-catalyzed highly regioselective hydration of alkynylsulfones comprises an efficient 100% atom-economic route to β-ketosulfones. The reaction proceeds under mild mercury-free conditions (Ph3PAuNTf2 0.5–5 mol%, THF, rt or 60 °C), it demonstrates a high functional group tolerance (more than 30 examples; yields up to 99%), and can be easily scaled up. The developed hydration methodology was successfully integrated into the one-pot syntheses of valuable heterocycles.

AB - Gold(I)-catalyzed highly regioselective hydration of alkynylsulfones comprises an efficient 100% atom-economic route to β-ketosulfones. The reaction proceeds under mild mercury-free conditions (Ph3PAuNTf2 0.5–5 mol%, THF, rt or 60 °C), it demonstrates a high functional group tolerance (more than 30 examples; yields up to 99%), and can be easily scaled up. The developed hydration methodology was successfully integrated into the one-pot syntheses of valuable heterocycles.

UR - https://pubs.rsc.org/en/content/articlelanding/2022/gc/d2gc00541g

M3 - Article

SP - 3314

EP - 3320

JO - Green Chemistry

JF - Green Chemistry

SN - 1463-9262

IS - 24

ER -

ID: 94491353