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Assessment of the physical properties, and the hydrogen, carbon, and oxygen content in plastics using energy-dispersive X-ray fluorescence spectrometry. / Aidene, Soraya; Semenov, Valentin; Kirsanov, Denis; Kirsanov, Dmitry; Panchuk, Vitaly.

In: Spectrochimica Acta - Part B Atomic Spectroscopy, Vol. 165, 105771, 03.2020.

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@article{77e921f7f07c48f9ba67584e5ff3201e,
title = "Assessment of the physical properties, and the hydrogen, carbon, and oxygen content in plastics using energy-dispersive X-ray fluorescence spectrometry",
abstract = "Energy-dispersive X-ray fluorescence spectrometry (EDX) is a widely used modern elemental analysis method. Most of the commercially produced EDX spectrometers cannot determine elements with atomic numbers below 11 (sodium). The EDX spectra contain scattering components and their intensity depends on the elemental composition and physical properties of the samples. The use of scattering as an analytical signal provides the opportunity to determine the integral characteristics of various samples. Since the light elements (with atomic numbers <11) also contribute to the scattering, it is possible to indirectly quantify these elements. In this study we demonstrate the use of X-ray scattering signals and chemometric tools to assess the physical properties and quantify the carbon, oxygen, and hydrogen content of various plastics.",
keywords = "Carbon, Chemometrics, EDX, Hydrogen, Plastics, CHEMOMETRICS, SPECTROSCOPY, CLASSIFICATION, SAMPLES, SCATTERING",
author = "Soraya Aidene and Valentin Semenov and Denis Kirsanov and Dmitry Kirsanov and Vitaly Panchuk",
year = "2020",
month = mar,
doi = "10.1016/j.sab.2020.105771",
language = "English",
volume = "165",
journal = "SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY",
issn = "0584-8547",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Assessment of the physical properties, and the hydrogen, carbon, and oxygen content in plastics using energy-dispersive X-ray fluorescence spectrometry

AU - Aidene, Soraya

AU - Semenov, Valentin

AU - Kirsanov, Denis

AU - Kirsanov, Dmitry

AU - Panchuk, Vitaly

PY - 2020/3

Y1 - 2020/3

N2 - Energy-dispersive X-ray fluorescence spectrometry (EDX) is a widely used modern elemental analysis method. Most of the commercially produced EDX spectrometers cannot determine elements with atomic numbers below 11 (sodium). The EDX spectra contain scattering components and their intensity depends on the elemental composition and physical properties of the samples. The use of scattering as an analytical signal provides the opportunity to determine the integral characteristics of various samples. Since the light elements (with atomic numbers <11) also contribute to the scattering, it is possible to indirectly quantify these elements. In this study we demonstrate the use of X-ray scattering signals and chemometric tools to assess the physical properties and quantify the carbon, oxygen, and hydrogen content of various plastics.

AB - Energy-dispersive X-ray fluorescence spectrometry (EDX) is a widely used modern elemental analysis method. Most of the commercially produced EDX spectrometers cannot determine elements with atomic numbers below 11 (sodium). The EDX spectra contain scattering components and their intensity depends on the elemental composition and physical properties of the samples. The use of scattering as an analytical signal provides the opportunity to determine the integral characteristics of various samples. Since the light elements (with atomic numbers <11) also contribute to the scattering, it is possible to indirectly quantify these elements. In this study we demonstrate the use of X-ray scattering signals and chemometric tools to assess the physical properties and quantify the carbon, oxygen, and hydrogen content of various plastics.

KW - Carbon

KW - Chemometrics

KW - EDX

KW - Hydrogen

KW - Plastics

KW - CHEMOMETRICS

KW - SPECTROSCOPY

KW - CLASSIFICATION

KW - SAMPLES

KW - SCATTERING

UR - http://www.scopus.com/inward/record.url?scp=85078074686&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/f6a260a1-0b29-32e6-a8bd-636433a963bd/

U2 - 10.1016/j.sab.2020.105771

DO - 10.1016/j.sab.2020.105771

M3 - Article

AN - SCOPUS:85078074686

VL - 165

JO - SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY

JF - SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY

SN - 0584-8547

M1 - 105771

ER -

ID: 51662206