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Assembly of Heterometallic AuICu2I2Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine. / Dayanova, Irina R.; Shamsieva, Aliia V.; Strelnik, Igor D.; Gerasimova, Tatiana P.; Kolesnikov, Ilya E.; Fayzullin, Robert R.; Islamov, Daut R.; Saifina, Alina F.; Musina, Elvira I.; Hey-Hawkins, Evamarie; Karasik, Andrey A.

In: Inorganic Chemistry, Vol. 60, No. 7, 05.04.2021, p. 5402-5411.

Research output: Contribution to journal › Article › peer-review

Harvard

Dayanova, IR, Shamsieva, AV, Strelnik, ID, Gerasimova, TP, Kolesnikov, IE, Fayzullin, RR, Islamov, DR, Saifina, AF, Musina, EI, Hey-Hawkins, E & Karasik, AA 2021, 'Assembly of Heterometallic AuICu2I2Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine', Inorganic Chemistry, vol. 60, no. 7, pp. 5402-5411. https://doi.org/10.1021/acs.inorgchem.1c00442

APA

Dayanova, I. R., Shamsieva, A. V., Strelnik, I. D., Gerasimova, T. P., Kolesnikov, I. E., Fayzullin, R. R., Islamov, D. R., Saifina, A. F., Musina, E. I., Hey-Hawkins, E., & Karasik, A. A. (2021). Assembly of Heterometallic AuICu2I2Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine. Inorganic Chemistry, 60(7), 5402-5411. https://doi.org/10.1021/acs.inorgchem.1c00442

Vancouver

Dayanova IR, Shamsieva AV, Strelnik ID, Gerasimova TP, Kolesnikov IE, Fayzullin RR et al. Assembly of Heterometallic AuICu2I2Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine. Inorganic Chemistry. 2021 Apr 5;60(7):5402-5411. https://doi.org/10.1021/acs.inorgchem.1c00442

Author

Dayanova, Irina R. ; Shamsieva, Aliia V. ; Strelnik, Igor D. ; Gerasimova, Tatiana P. ; Kolesnikov, Ilya E. ; Fayzullin, Robert R. ; Islamov, Daut R. ; Saifina, Alina F. ; Musina, Elvira I. ; Hey-Hawkins, Evamarie ; Karasik, Andrey A. / Assembly of Heterometallic AuICu2I2Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine. In: Inorganic Chemistry. 2021 ; Vol. 60, No. 7. pp. 5402-5411.

BibTeX

@article{c83b430c3dd04fd7bc74eda4a28f86ad,
title = "Assembly of Heterometallic AuICu2I2Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine",
abstract = "The row of metallocyclic dinuclear gold(I) complexes with cyclic diphosphines, namely, P-pyridylethyl-substituted 1,5-diaza-3,7-diphosphacyclooctanes, has been obtained. Further interaction of the dinuclear gold(I) complexes with copper(I) iodide gave the first examples of hexanuclear AuI/CuI complexes containing two unusual trinuclear AuICu2I2 fragments. The structures of di- and hexanuclear complexes were confirmed by NMR spectroscopy, ESI mass spectrometry, elemental analysis, and single-crystal X-ray diffraction. All of the obtained complexes are moderate emitters in the solid state. Dinuclear gold(I) complexes displayed a greenish emission with the maxima in the emission spectra at ca. 550 nm. The obtained hexanuclear heterobimetallic AuI/CuI complexes are triplet solid-state blue emitters with the maximum in the emission spectra at 463 and 484 nm. According to the TD-DFT calculations, the observed emission of all studied complexes had a triplet origin and was caused by the 3CC or 3(MLCT) T1 → S0 transitions for dinuclear and hexanuclear complexes, respectively. ",
keywords = "LUMINESCENT COMPLEXES, BASIS-SETS, GOLD(I), LIGHT, CLUSTERS, COPPER, EMISSION, LIGANDS, PSEUDOPOTENTIALS, CONSTRUCTION",
author = "Dayanova, {Irina R.} and Shamsieva, {Aliia V.} and Strelnik, {Igor D.} and Gerasimova, {Tatiana P.} and Kolesnikov, {Ilya E.} and Fayzullin, {Robert R.} and Islamov, {Daut R.} and Saifina, {Alina F.} and Musina, {Elvira I.} and Evamarie Hey-Hawkins and Karasik, {Andrey A.}",
note = "Publisher Copyright: {\textcopyright} ",
year = "2021",
month = apr,
day = "5",
doi = "10.1021/acs.inorgchem.1c00442",
language = "English",
volume = "60",
pages = "5402--5411",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "7",

}

RIS

TY - JOUR

T1 - Assembly of Heterometallic AuICu2I2Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine

AU - Dayanova, Irina R.

AU - Shamsieva, Aliia V.

AU - Strelnik, Igor D.

AU - Gerasimova, Tatiana P.

AU - Kolesnikov, Ilya E.

AU - Fayzullin, Robert R.

AU - Islamov, Daut R.

AU - Saifina, Alina F.

AU - Musina, Elvira I.

AU - Hey-Hawkins, Evamarie

AU - Karasik, Andrey A.

N1 - Publisher Copyright: ©

PY - 2021/4/5

Y1 - 2021/4/5

N2 - The row of metallocyclic dinuclear gold(I) complexes with cyclic diphosphines, namely, P-pyridylethyl-substituted 1,5-diaza-3,7-diphosphacyclooctanes, has been obtained. Further interaction of the dinuclear gold(I) complexes with copper(I) iodide gave the first examples of hexanuclear AuI/CuI complexes containing two unusual trinuclear AuICu2I2 fragments. The structures of di- and hexanuclear complexes were confirmed by NMR spectroscopy, ESI mass spectrometry, elemental analysis, and single-crystal X-ray diffraction. All of the obtained complexes are moderate emitters in the solid state. Dinuclear gold(I) complexes displayed a greenish emission with the maxima in the emission spectra at ca. 550 nm. The obtained hexanuclear heterobimetallic AuI/CuI complexes are triplet solid-state blue emitters with the maximum in the emission spectra at 463 and 484 nm. According to the TD-DFT calculations, the observed emission of all studied complexes had a triplet origin and was caused by the 3CC or 3(MLCT) T1 → S0 transitions for dinuclear and hexanuclear complexes, respectively.

AB - The row of metallocyclic dinuclear gold(I) complexes with cyclic diphosphines, namely, P-pyridylethyl-substituted 1,5-diaza-3,7-diphosphacyclooctanes, has been obtained. Further interaction of the dinuclear gold(I) complexes with copper(I) iodide gave the first examples of hexanuclear AuI/CuI complexes containing two unusual trinuclear AuICu2I2 fragments. The structures of di- and hexanuclear complexes were confirmed by NMR spectroscopy, ESI mass spectrometry, elemental analysis, and single-crystal X-ray diffraction. All of the obtained complexes are moderate emitters in the solid state. Dinuclear gold(I) complexes displayed a greenish emission with the maxima in the emission spectra at ca. 550 nm. The obtained hexanuclear heterobimetallic AuI/CuI complexes are triplet solid-state blue emitters with the maximum in the emission spectra at 463 and 484 nm. According to the TD-DFT calculations, the observed emission of all studied complexes had a triplet origin and was caused by the 3CC or 3(MLCT) T1 → S0 transitions for dinuclear and hexanuclear complexes, respectively.

KW - LUMINESCENT COMPLEXES

KW - BASIS-SETS

KW - GOLD(I)

KW - LIGHT

KW - CLUSTERS

KW - COPPER

KW - EMISSION

KW - LIGANDS

KW - PSEUDOPOTENTIALS

KW - CONSTRUCTION

UR - http://www.scopus.com/inward/record.url?scp=85103992689&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.1c00442

DO - 10.1021/acs.inorgchem.1c00442

M3 - Article

C2 - 33759505

AN - SCOPUS:85103992689

VL - 60

SP - 5402

EP - 5411

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 7

ER -

ID: 86366847