The character of the temperature dependences of the retention indices RI(Т) of polar sorbates on nonpolar stationary phases was found to depend on the dosed amounts of sorbates, but not on column overloading. A physicochemical model was suggested to explain the observed anomalies in RI(Т).

Translated title of the contributionАномальная температурная зависимость газохроматографических индексов удерживания полярных соединений на неполярных фазах
Original languageEnglish
Pages (from-to)1074-1080
Number of pages7
JournalRussian Journal of Physical Chemistry A
Volume90
Issue number5
DOIs
StatePublished - 1 May 2016

    Scopus subject areas

  • Physical and Theoretical Chemistry

    Research areas

  • anomalous temperature dependence, chromatographic retention indices, gas chromatography, nonpolar stationary phases, polar sorbates

ID: 9344221