Research output: Contribution to journal › Article
Annealing effect: Controlled modification of the structure, composition and plasmon resonance of hybrid Au-Ag/C nanostructures. / Manshina, A.; Povolotskiy, A.; Povolotckaia, A.; Kireev, A.; Petrov, Yu.; Tunik, S.
In: Applied Surface Science, Vol. 353, 2015, p. 11-16.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Annealing effect: Controlled modification of the structure, composition and plasmon resonance of hybrid Au-Ag/C nanostructures
AU - Manshina, A.
AU - Povolotskiy, A.
AU - Povolotckaia, A.
AU - Kireev, A.
AU - Petrov, Yu.
AU - Tunik, S.
PY - 2015
Y1 - 2015
N2 - © 2015 Elsevier B.V. All rights reserved.Here we present a novel approach to the synthesis of hybrid Au-Ag/C nanoparticles (NPs) which were found to be carbon nanospheres containing dispersed Au-Ag bimetallic nanoparticles (1-5 nm). The Au-Ag/C NPs were obtained by laser-induced liquid phase deposition from solutions of supramolecular complex. It was revealed that subsequent annealing procedure of Au-Ag/C NPs at various temperatures over the range 100-600 °C allows variation and directed control of NPs' morphology and composition (relative contents of principal components). For nanoscale carbon material the critical evaporation temperature was found to be about 300 °C, while for Ag and Au components - 500 °C and 600 °C accordingly. The morphology and composition variation makes possible tuning of the surface plasmon resonance characteristics that opens an efficient way of the NPs' functional properties control, like for example Surface-Enhanced Raman Scattering (SERS). It was found that the obtained hybrid Au
AB - © 2015 Elsevier B.V. All rights reserved.Here we present a novel approach to the synthesis of hybrid Au-Ag/C nanoparticles (NPs) which were found to be carbon nanospheres containing dispersed Au-Ag bimetallic nanoparticles (1-5 nm). The Au-Ag/C NPs were obtained by laser-induced liquid phase deposition from solutions of supramolecular complex. It was revealed that subsequent annealing procedure of Au-Ag/C NPs at various temperatures over the range 100-600 °C allows variation and directed control of NPs' morphology and composition (relative contents of principal components). For nanoscale carbon material the critical evaporation temperature was found to be about 300 °C, while for Ag and Au components - 500 °C and 600 °C accordingly. The morphology and composition variation makes possible tuning of the surface plasmon resonance characteristics that opens an efficient way of the NPs' functional properties control, like for example Surface-Enhanced Raman Scattering (SERS). It was found that the obtained hybrid Au
U2 - 10.1016/j.apsusc.2015.06.048
DO - 10.1016/j.apsusc.2015.06.048
M3 - Article
VL - 353
SP - 11
EP - 16
JO - Applied Surface Science
JF - Applied Surface Science
SN - 0169-4332
ER -
ID: 4008832