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By analyzing the dielectric nonlinearity with the Landau thermodynamic expansion, we find a simple and direct way to assess the importance of the eighth-order term. Following this approach, it is demonstrated that the eighth-order term is essential for the adequate description of the paraelectric-ferroelectric phase transition of BaTiO3. The temperature dependence of the quartic coefficient β is accordingly reconsidered and is strongly evidenced by the change of its sign above 165°C. All these findings attest to the anomalously strong polarization anharmonicity of this material, which is unexpected for classical displacive ferroelectrics.
| Original language | English |
|---|---|
| Article number | 132103 |
| Journal | Physical Review B - Condensed Matter and Materials Physics |
| Volume | 73 |
| Issue number | 13 |
| DOIs | |
| State | Published - 2006 |
ID: 5571569