• Y. L. Wang
  • A. K. Tagantsev
  • D. Damjanovic
  • N. Setter
  • V. K. Yarmarkin
  • A. I. Sokolov

By analyzing the dielectric nonlinearity with the Landau thermodynamic expansion, we find a simple and direct way to assess the importance of the eighth-order term. Following this approach, it is demonstrated that the eighth-order term is essential for the adequate description of the paraelectric-ferroelectric phase transition of BaTiO3. The temperature dependence of the quartic coefficient β is accordingly reconsidered and is strongly evidenced by the change of its sign above 165°C. All these findings attest to the anomalously strong polarization anharmonicity of this material, which is unexpected for classical displacive ferroelectrics.

Original languageEnglish
Article number132103
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume73
Issue number13
DOIs
StatePublished - 2006

    Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

ID: 5571569