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An unprecedented pseudo-C3-symmetric cage-like cluster [Cu7I11]4–. / Artem’ev, Alexander V.; Yu. Baranov, Andrey; Novikov, Alexander S.; Berezin, Alexey S.; Yu. Bagryanskaya, Irina.

In: Inorganic Chemistry Communications, Vol. 168, 112958, 01.10.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Artem’ev, AV, Yu. Baranov, A, Novikov, AS, Berezin, AS & Yu. Bagryanskaya, I 2024, 'An unprecedented pseudo-C3-symmetric cage-like cluster [Cu7I11]4–', Inorganic Chemistry Communications, vol. 168, 112958. https://doi.org/10.1016/j.inoche.2024.112958

APA

Artem’ev, A. V., Yu. Baranov, A., Novikov, A. S., Berezin, A. S., & Yu. Bagryanskaya, I. (2024). An unprecedented pseudo-C3-symmetric cage-like cluster [Cu7I11]4–. Inorganic Chemistry Communications, 168, [112958]. https://doi.org/10.1016/j.inoche.2024.112958

Vancouver

Artem’ev AV, Yu. Baranov A, Novikov AS, Berezin AS, Yu. Bagryanskaya I. An unprecedented pseudo-C3-symmetric cage-like cluster [Cu7I11]4–. Inorganic Chemistry Communications. 2024 Oct 1;168. 112958. https://doi.org/10.1016/j.inoche.2024.112958

Author

Artem’ev, Alexander V. ; Yu. Baranov, Andrey ; Novikov, Alexander S. ; Berezin, Alexey S. ; Yu. Bagryanskaya, Irina. / An unprecedented pseudo-C3-symmetric cage-like cluster [Cu7I11]4–. In: Inorganic Chemistry Communications. 2024 ; Vol. 168.

BibTeX

@article{25c6ded9009e48a2b472c8974ecc4cb1,
title = "An unprecedented pseudo-C3-symmetric cage-like cluster [Cu7I11]4–",
abstract = "An unprecedented cluster [Cu7I11]4– with a pseudo-C3-symmetric cage-like structure has been identified in an ionic salt with [1,4-(Ph3PCH2)2C6H4]2+ cations. The [Cu7I11]4– anion is composed of a six-point star Cu6(µ6-I)(µ2-I)6 capped by a CuI4 tetrahedron. A Cu6 hexagonal subunit of [Cu7I11]4– exhibits strong Cu∙∙∙Cu interactions (dCu–Cu = 2.457–2.958 {\AA}) as evidenced by QTAIM analysis. At 25 °C, the new [Cu7I11]4– cluster emits a weak phosphorescence. In addition, two [Cu2I4]2– iodocuprates supported by [1,4-(Ph3PCH2)2(C6H4)n]2+ cations (n = 1 or 2) are reported, showing no Cu∙∙∙Cu interactions.",
keywords = "Clusters, Copper(I), Cuprophilic interactions, Iodocurpates(I), Phosphonium salts, Phosphorescence",
author = "Artem{\textquoteright}ev, {Alexander V.} and {Yu. Baranov}, Andrey and Novikov, {Alexander S.} and Berezin, {Alexey S.} and {Yu. Bagryanskaya}, Irina",
year = "2024",
month = oct,
day = "1",
doi = "10.1016/j.inoche.2024.112958",
language = "English",
volume = "168",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - An unprecedented pseudo-C3-symmetric cage-like cluster [Cu7I11]4–

AU - Artem’ev, Alexander V.

AU - Yu. Baranov, Andrey

AU - Novikov, Alexander S.

AU - Berezin, Alexey S.

AU - Yu. Bagryanskaya, Irina

PY - 2024/10/1

Y1 - 2024/10/1

N2 - An unprecedented cluster [Cu7I11]4– with a pseudo-C3-symmetric cage-like structure has been identified in an ionic salt with [1,4-(Ph3PCH2)2C6H4]2+ cations. The [Cu7I11]4– anion is composed of a six-point star Cu6(µ6-I)(µ2-I)6 capped by a CuI4 tetrahedron. A Cu6 hexagonal subunit of [Cu7I11]4– exhibits strong Cu∙∙∙Cu interactions (dCu–Cu = 2.457–2.958 Å) as evidenced by QTAIM analysis. At 25 °C, the new [Cu7I11]4– cluster emits a weak phosphorescence. In addition, two [Cu2I4]2– iodocuprates supported by [1,4-(Ph3PCH2)2(C6H4)n]2+ cations (n = 1 or 2) are reported, showing no Cu∙∙∙Cu interactions.

AB - An unprecedented cluster [Cu7I11]4– with a pseudo-C3-symmetric cage-like structure has been identified in an ionic salt with [1,4-(Ph3PCH2)2C6H4]2+ cations. The [Cu7I11]4– anion is composed of a six-point star Cu6(µ6-I)(µ2-I)6 capped by a CuI4 tetrahedron. A Cu6 hexagonal subunit of [Cu7I11]4– exhibits strong Cu∙∙∙Cu interactions (dCu–Cu = 2.457–2.958 Å) as evidenced by QTAIM analysis. At 25 °C, the new [Cu7I11]4– cluster emits a weak phosphorescence. In addition, two [Cu2I4]2– iodocuprates supported by [1,4-(Ph3PCH2)2(C6H4)n]2+ cations (n = 1 or 2) are reported, showing no Cu∙∙∙Cu interactions.

KW - Clusters

KW - Copper(I)

KW - Cuprophilic interactions

KW - Iodocurpates(I)

KW - Phosphonium salts

KW - Phosphorescence

UR - https://www.mendeley.com/catalogue/445aa2a5-b30b-3d03-8314-5f3595e89869/

U2 - 10.1016/j.inoche.2024.112958

DO - 10.1016/j.inoche.2024.112958

M3 - Article

VL - 168

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

M1 - 112958

ER -

ID: 122849760