Research output: Contribution to journal › Article › peer-review
An Electrooptical Method for Studying the Coagulation of Nanodisperse Systems : Formation of Aggregates of Graphite Particles in Aqueous Electrolytes. / Vezo, O. S.; Voitylov, A. V.; Voitylov, V. V.; Petrov, M. P.; Trusov, A. A.
In: OPTICS AND SPECTROSCOPY, Vol. 128, No. 6, 01.06.2020, p. 719-728.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - An Electrooptical Method for Studying the Coagulation of Nanodisperse Systems
T2 - Formation of Aggregates of Graphite Particles in Aqueous Electrolytes
AU - Vezo, O. S.
AU - Voitylov, A. V.
AU - Voitylov, V. V.
AU - Petrov, M. P.
AU - Trusov, A. A.
N1 - Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/6/1
Y1 - 2020/6/1
N2 - Abstract: We demonstrate that the electrooptical method can be used to study the coagulation of liquid nanodisperse systems, in particular, colloids and suspensions. Two electrooptical effects have been used—one dependent and one independent of the polarization of light passing through the system in the electric field. The results of study of the coagulation kinetics at its early stage, associated with the formation of pair aggregates from graphite particles suspended in AlCl3 and Th(NO3)4 aqueous electrolytes are presented. We show that the systems are stable in a wide range of electrolyte concentrations and lose their stability in a narrow range in which the electrokinetic potential of particles does not exceed 5 mV. We show that the electrooptically determined dependences of the particle concentration on the coagulation time at the isoelectric point agree well with the Smoluchowski theory of rapid coagulation.
AB - Abstract: We demonstrate that the electrooptical method can be used to study the coagulation of liquid nanodisperse systems, in particular, colloids and suspensions. Two electrooptical effects have been used—one dependent and one independent of the polarization of light passing through the system in the electric field. The results of study of the coagulation kinetics at its early stage, associated with the formation of pair aggregates from graphite particles suspended in AlCl3 and Th(NO3)4 aqueous electrolytes are presented. We show that the systems are stable in a wide range of electrolyte concentrations and lose their stability in a narrow range in which the electrokinetic potential of particles does not exceed 5 mV. We show that the electrooptically determined dependences of the particle concentration on the coagulation time at the isoelectric point agree well with the Smoluchowski theory of rapid coagulation.
KW - coagulation
KW - colloids and suspensions
KW - electrooptical effects
KW - graphite particles
KW - pair aggregates
KW - static and dynamic light scattering
KW - SINGLE
KW - DIAMOND
KW - DISPERSION
KW - FIELD
KW - COLLOIDAL PARTICLES
KW - LIGHT-SCATTERING
UR - http://www.scopus.com/inward/record.url?scp=85087981195&partnerID=8YFLogxK
U2 - 10.1134/S0030400X20060247
DO - 10.1134/S0030400X20060247
M3 - Article
AN - SCOPUS:85087981195
VL - 128
SP - 719
EP - 728
JO - OPTICS AND SPECTROSCOPY
JF - OPTICS AND SPECTROSCOPY
SN - 0030-400X
IS - 6
ER -
ID: 69883944