Research output: Contribution to journal › Article › peer-review
The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime = acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH = NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH = NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings.
Original language | English |
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Pages (from-to) | 387-392 |
Number of pages | 6 |
Journal | Transition Metal Chemistry |
Volume | 41 |
Issue number | 4 |
DOIs | |
State | Published - 1 May 2016 |
ID: 7559929