Research output: Contribution to journal › Article › peer-review
Aluminium trichloride-promoted tandem hydroarylation–ionic hydrogenation of 3-arylpropynoic acid derivatives and 4-phenylbut-3-yn-2-one. / Ignatova, Irina I.; Khoroshilova, Olesya V.; Vasilyev, Aleksander V.
In: Mendeleev Communications, Vol. 33, No. 1, 12.01.2023, p. 27-29.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Aluminium trichloride-promoted tandem hydroarylation–ionic hydrogenation of 3-arylpropynoic acid derivatives and 4-phenylbut-3-yn-2-one
AU - Ignatova, Irina I.
AU - Khoroshilova, Olesya V.
AU - Vasilyev, Aleksander V.
N1 - Ignatova I.I., Khoroshilova O.V., Vasilyev A.V. Aliminium trichloride-promoted tandem hydroarylation-ionic hydrogenation of 3-arylpropynoic acid derivatives and 4-phenylbut-3-yn-2-one. Mendeleev Communications. 2023, V. 33, N. 1, P. 27-29.
PY - 2023/1/12
Y1 - 2023/1/12
N2 - Reactions of 3-arylpropynoic acid derivatives and conjugated acetylene ketones with arenes and cyclohexane under the action of AlCl3 at room temperature for 15 h afford the corresponding products of one-pot tandem hydroarylation–ionic hydrogenation of the acetylene bond of the starting compounds in 42–98% yields. This reaction is accompanied by aryl group exchange process under acidic conditions.
AB - Reactions of 3-arylpropynoic acid derivatives and conjugated acetylene ketones with arenes and cyclohexane under the action of AlCl3 at room temperature for 15 h afford the corresponding products of one-pot tandem hydroarylation–ionic hydrogenation of the acetylene bond of the starting compounds in 42–98% yields. This reaction is accompanied by aryl group exchange process under acidic conditions.
KW - arylpropynoic acids
KW - carbocations
KW - hydroarylation
KW - ionic hydrogenation
KW - superelectrophilic activation
KW - ynones
UR - https://www.mendeley.com/catalogue/3a155219-9343-3255-93ce-b92f78868700/
U2 - 10.1016/j.mencom.2023.01.008
DO - 10.1016/j.mencom.2023.01.008
M3 - Article
VL - 33
SP - 27
EP - 29
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 1
ER -
ID: 113728663