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Alkynylated Palladium(II) and Platinum(II) Acyclic Diaminocarbene Complexes and Their Intramolecular Cyclization via trans-Chlorometalation. / Мельник, Мария Вячеславовна; Михайлов, Владимир Николаевич; Новиков, Александр Сергеевич; Кинжалов, Михаил Андреевич; Бунев, Александр Сиясатович; Крюкова, Мария Александровна; Сорокоумов, Виктор Николаевич; Балова, Ирина Анатольевна.

In: Organometallics, Vol. 44, No. 1, 01.2025, p. 268-278.

Research output: Contribution to journal › Article › peer-review

Harvard

Мельник, МВ, Михайлов, ВН, Новиков, АС, Кинжалов, МА, Бунев, АС, Крюкова, МА, Сорокоумов, ВН & Балова, ИА 2025, 'Alkynylated Palladium(II) and Platinum(II) Acyclic Diaminocarbene Complexes and Their Intramolecular Cyclization via trans-Chlorometalation', Organometallics, vol. 44, no. 1, pp. 268-278. https://doi.org/10.1021/acs.organomet.4c00440

APA

Мельник, М. В., Михайлов, В. Н., Новиков, А. С., Кинжалов, М. А., Бунев, А. С., Крюкова, М. А., Сорокоумов, В. Н., & Балова, И. А. (2025). Alkynylated Palladium(II) and Platinum(II) Acyclic Diaminocarbene Complexes and Their Intramolecular Cyclization via trans-Chlorometalation. Organometallics, 44(1), 268-278. https://doi.org/10.1021/acs.organomet.4c00440

Vancouver

Мельник МВ, Михайлов ВН, Новиков АС, Кинжалов МА, Бунев АС, Крюкова МА et al. Alkynylated Palladium(II) and Platinum(II) Acyclic Diaminocarbene Complexes and Their Intramolecular Cyclization via trans-Chlorometalation. Organometallics. 2025 Jan;44(1):268-278. https://doi.org/10.1021/acs.organomet.4c00440

Author

Мельник, Мария Вячеславовна ; Михайлов, Владимир Николаевич ; Новиков, Александр Сергеевич ; Кинжалов, Михаил Андреевич ; Бунев, Александр Сиясатович ; Крюкова, Мария Александровна ; Сорокоумов, Виктор Николаевич ; Балова, Ирина Анатольевна. / Alkynylated Palladium(II) and Platinum(II) Acyclic Diaminocarbene Complexes and Their Intramolecular Cyclization via trans-Chlorometalation. In: Organometallics. 2025 ; Vol. 44, No. 1. pp. 268-278.

BibTeX

@article{18cfa21d85a9455586165b622de22d3c,
title = "Alkynylated Palladium(II) and Platinum(II) Acyclic Diaminocarbene Complexes and Their Intramolecular Cyclization via trans-Chlorometalation",
abstract = "This study presents the synthesis of N-alkynylated acyclic diaminocarbene (ADC) complexes of palladium(II) and platinum(II) and their intramolecular cyclization via trans-chlorometalation. The reactions of propargylamines with bis-isocyanide complexes of Pd(II) and Pt(II) produced the desired ADC complexes in good yields. The NH,NH-diaminocarbene complexes were unstable in solution and underwent intramolecular cyclization into chlorometalated products. These findings provide a novel route to stable N-alkynylated ADC complexes with potential applications in catalysis and medicinal chemistry. The complexes synthesized exhibit promising structural and reactive properties suitable for further exploration.",
author = "Мельник, {Мария Вячеславовна} and Михайлов, {Владимир Николаевич} and Новиков, {Александр Сергеевич} and Кинжалов, {Михаил Андреевич} and Бунев, {Александр Сиясатович} and Крюкова, {Мария Александровна} and Сорокоумов, {Виктор Николаевич} and Балова, {Ирина Анатольевна}",
year = "2025",
month = jan,
doi = "10.1021/acs.organomet.4c00440",
language = "English",
volume = "44",
pages = "268--278",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "1",

}

RIS

TY - JOUR

T1 - Alkynylated Palladium(II) and Platinum(II) Acyclic Diaminocarbene Complexes and Their Intramolecular Cyclization via trans-Chlorometalation

AU - Мельник, Мария Вячеславовна

AU - Михайлов, Владимир Николаевич

AU - Новиков, Александр Сергеевич

AU - Кинжалов, Михаил Андреевич

AU - Бунев, Александр Сиясатович

AU - Крюкова, Мария Александровна

AU - Сорокоумов, Виктор Николаевич

AU - Балова, Ирина Анатольевна

PY - 2025/1

Y1 - 2025/1

N2 - This study presents the synthesis of N-alkynylated acyclic diaminocarbene (ADC) complexes of palladium(II) and platinum(II) and their intramolecular cyclization via trans-chlorometalation. The reactions of propargylamines with bis-isocyanide complexes of Pd(II) and Pt(II) produced the desired ADC complexes in good yields. The NH,NH-diaminocarbene complexes were unstable in solution and underwent intramolecular cyclization into chlorometalated products. These findings provide a novel route to stable N-alkynylated ADC complexes with potential applications in catalysis and medicinal chemistry. The complexes synthesized exhibit promising structural and reactive properties suitable for further exploration.

AB - This study presents the synthesis of N-alkynylated acyclic diaminocarbene (ADC) complexes of palladium(II) and platinum(II) and their intramolecular cyclization via trans-chlorometalation. The reactions of propargylamines with bis-isocyanide complexes of Pd(II) and Pt(II) produced the desired ADC complexes in good yields. The NH,NH-diaminocarbene complexes were unstable in solution and underwent intramolecular cyclization into chlorometalated products. These findings provide a novel route to stable N-alkynylated ADC complexes with potential applications in catalysis and medicinal chemistry. The complexes synthesized exhibit promising structural and reactive properties suitable for further exploration.

UR - https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.4c00440

UR - https://www.mendeley.com/catalogue/272ee2a4-43e8-34c6-bcf2-16f8f050e07d/

U2 - 10.1021/acs.organomet.4c00440

DO - 10.1021/acs.organomet.4c00440

M3 - Article

VL - 44

SP - 268

EP - 278

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 1

ER -

ID: 128640836