Research output: Contribution to journal › Article › peer-review
Ag2S-As2S3-TlI chalcogenide glasses as perspective material for solid-state chemical sensors. / Kalyagin, D. S.; Ermolenko, Yu E.; Alekseev, I. E.; Bychkov, E. A.; Krotov, S. A.; Mel'Nikova, N. A.; Murin, I. V.; Vlasov, Yu G.
In: Russian Journal of Applied Chemistry, Vol. 87, No. 8, 2014, p. 1044-1048.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Ag2S-As2S3-TlI chalcogenide glasses as perspective material for solid-state chemical sensors
AU - Kalyagin, D. S.
AU - Ermolenko, Yu E.
AU - Alekseev, I. E.
AU - Bychkov, E. A.
AU - Krotov, S. A.
AU - Mel'Nikova, N. A.
AU - Murin, I. V.
AU - Vlasov, Yu G.
N1 - Publisher Copyright: © 2014 Pleiades Publishing, Ltd.
PY - 2014
Y1 - 2014
N2 - Modern research techniques with radioactive isotopes were used to study the transport characteristics, (conductivity and diffusion) in chalcogenide membrane materials of the Ag2S-As2S3-TlI system. It was demonstrated that, on raising the silver sulfide concentration in a glass, the total electrical conductivity grows by two orders of magnitude, which is due to the pronounced change of the band structure and to the increase in the electronic component of the conductivity. New chemical sensors for determination Tl ions in solutions were developed on the basis of these solid-state studies.
AB - Modern research techniques with radioactive isotopes were used to study the transport characteristics, (conductivity and diffusion) in chalcogenide membrane materials of the Ag2S-As2S3-TlI system. It was demonstrated that, on raising the silver sulfide concentration in a glass, the total electrical conductivity grows by two orders of magnitude, which is due to the pronounced change of the band structure and to the increase in the electronic component of the conductivity. New chemical sensors for determination Tl ions in solutions were developed on the basis of these solid-state studies.
UR - http://www.scopus.com/inward/record.url?scp=84912017988&partnerID=8YFLogxK
U2 - 10.1134/S1070427214080060
DO - 10.1134/S1070427214080060
M3 - Article
VL - 87
SP - 1044
EP - 1048
JO - Russian Journal of Applied Chemistry
JF - Russian Journal of Applied Chemistry
SN - 1070-4272
IS - 8
ER -
ID: 7012870