Research output: Contribution to journal › Article › peer-review
Advances in thermodynamics of solid surfaces. / Rusanov, A. I.
In: Pure and Applied Chemistry, Vol. 61, No. 11, 01.01.1989, p. 1945-1948.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Advances in thermodynamics of solid surfaces
AU - Rusanov, A. I.
PY - 1989/1/1
Y1 - 1989/1/1
N2 - The thermodynamics of solid surfaces is the least developed part of the surface thermodynamics. The Gibbs adsorption equation referred only to fluid systems, and an analogous equation for deformable solids was derived considerably later. Its general interpretation is complemented now by the concept of the tensorial anisotropic chemical potential corresponding to an anisotropic deformation state in a solid. Surface stresses produce the mechanical surface tension of which the direct measurement was a great problem up to now. The first method of measuring surface tension of solids has been proposed very recently and is based on the effect of deformation on solubility.
AB - The thermodynamics of solid surfaces is the least developed part of the surface thermodynamics. The Gibbs adsorption equation referred only to fluid systems, and an analogous equation for deformable solids was derived considerably later. Its general interpretation is complemented now by the concept of the tensorial anisotropic chemical potential corresponding to an anisotropic deformation state in a solid. Surface stresses produce the mechanical surface tension of which the direct measurement was a great problem up to now. The first method of measuring surface tension of solids has been proposed very recently and is based on the effect of deformation on solubility.
UR - http://www.scopus.com/inward/record.url?scp=0039900501&partnerID=8YFLogxK
U2 - 10.1351/pac198961111945
DO - 10.1351/pac198961111945
M3 - Article
AN - SCOPUS:0039900501
VL - 61
SP - 1945
EP - 1948
JO - Pure and Applied Chemistry
JF - Pure and Applied Chemistry
SN - 0033-4545
IS - 11
ER -
ID: 95723817