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Adducts of a Sterically Hindered Tellurium(IV) Catecholate with Diimines. / Petrov, Pavel A.; Filippova, Elizaveta A.; Sukhikh, Taisiya Sergeevna; Sheven’, Dmitriy G.; Novikov, Alexander S.

In: New Journal of Chemistry, Vol. 48, No. 35, 02.08.2024, p. 15483-15492.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Filippova, EA, Sukhikh, TS, Sheven’, DG & Novikov, AS 2024, 'Adducts of a Sterically Hindered Tellurium(IV) Catecholate with Diimines', New Journal of Chemistry, vol. 48, no. 35, pp. 15483-15492. https://doi.org/10.1039/d4nj02469a

APA

Petrov, P. A., Filippova, E. A., Sukhikh, T. S., Sheven’, D. G., & Novikov, A. S. (2024). Adducts of a Sterically Hindered Tellurium(IV) Catecholate with Diimines. New Journal of Chemistry, 48(35), 15483-15492. https://doi.org/10.1039/d4nj02469a

Vancouver

Petrov PA, Filippova EA, Sukhikh TS, Sheven’ DG, Novikov AS. Adducts of a Sterically Hindered Tellurium(IV) Catecholate with Diimines. New Journal of Chemistry. 2024 Aug 2;48(35):15483-15492. https://doi.org/10.1039/d4nj02469a

Author

Petrov, Pavel A. ; Filippova, Elizaveta A. ; Sukhikh, Taisiya Sergeevna ; Sheven’, Dmitriy G. ; Novikov, Alexander S. / Adducts of a Sterically Hindered Tellurium(IV) Catecholate with Diimines. In: New Journal of Chemistry. 2024 ; Vol. 48, No. 35. pp. 15483-15492.

BibTeX

@article{30c10bc45e7344fc98f59d336534fbf6,
title = "Adducts of a Sterically Hindered Tellurium(IV) Catecholate with Diimines",
abstract = "Adducts of sterically hindered tellurium catecholate Te(Cat36)2 (Cat36 = 3,6-di-tert-butyl-catecholate) with diimine ligands were isolated and characterized by means of single crystal X-ray diffraction along with IR, UV-vis-NIR and NMR (1H, 125Te) spectroscopy. Adducts with 1,10-phenanthroline (phen) and 5,6-epoxy-5,6-dihydro-[1,10]phenanthroline (phenO) feature a very rare μ-κ2N,N′:κ2N,N′-bridging coordination mode of diimines. The adduct with 2,2′-bipyrimidine (bpm) is dimeric with a μ-κ2N,N′:κ2N,N′-bridging coordination mode of bpm, while with 4,7-dimethyl-1,10-phenanthroline (phenMe2) a dimer is formed due to Te-(η6-C6) contacts. Te⋯N and Te⋯C interactions between Te(Cat36)2 and the diimines were found to be attractive and non-covalent (DFT and QTAIM). In accordance with the weakness of Te⋯N interactions, no ligand-to-ligand charge transfer (LLCT) bands were observed in the electronic spectra of the adducts.",
author = "Petrov, {Pavel A.} and Filippova, {Elizaveta A.} and Sukhikh, {Taisiya Sergeevna} and Sheven{\textquoteright}, {Dmitriy G.} and Novikov, {Alexander S.}",
year = "2024",
month = aug,
day = "2",
doi = "10.1039/d4nj02469a",
language = "English",
volume = "48",
pages = "15483--15492",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "Royal Society of Chemistry",
number = "35",

}

RIS

TY - JOUR

T1 - Adducts of a Sterically Hindered Tellurium(IV) Catecholate with Diimines

AU - Petrov, Pavel A.

AU - Filippova, Elizaveta A.

AU - Sukhikh, Taisiya Sergeevna

AU - Sheven’, Dmitriy G.

AU - Novikov, Alexander S.

PY - 2024/8/2

Y1 - 2024/8/2

N2 - Adducts of sterically hindered tellurium catecholate Te(Cat36)2 (Cat36 = 3,6-di-tert-butyl-catecholate) with diimine ligands were isolated and characterized by means of single crystal X-ray diffraction along with IR, UV-vis-NIR and NMR (1H, 125Te) spectroscopy. Adducts with 1,10-phenanthroline (phen) and 5,6-epoxy-5,6-dihydro-[1,10]phenanthroline (phenO) feature a very rare μ-κ2N,N′:κ2N,N′-bridging coordination mode of diimines. The adduct with 2,2′-bipyrimidine (bpm) is dimeric with a μ-κ2N,N′:κ2N,N′-bridging coordination mode of bpm, while with 4,7-dimethyl-1,10-phenanthroline (phenMe2) a dimer is formed due to Te-(η6-C6) contacts. Te⋯N and Te⋯C interactions between Te(Cat36)2 and the diimines were found to be attractive and non-covalent (DFT and QTAIM). In accordance with the weakness of Te⋯N interactions, no ligand-to-ligand charge transfer (LLCT) bands were observed in the electronic spectra of the adducts.

AB - Adducts of sterically hindered tellurium catecholate Te(Cat36)2 (Cat36 = 3,6-di-tert-butyl-catecholate) with diimine ligands were isolated and characterized by means of single crystal X-ray diffraction along with IR, UV-vis-NIR and NMR (1H, 125Te) spectroscopy. Adducts with 1,10-phenanthroline (phen) and 5,6-epoxy-5,6-dihydro-[1,10]phenanthroline (phenO) feature a very rare μ-κ2N,N′:κ2N,N′-bridging coordination mode of diimines. The adduct with 2,2′-bipyrimidine (bpm) is dimeric with a μ-κ2N,N′:κ2N,N′-bridging coordination mode of bpm, while with 4,7-dimethyl-1,10-phenanthroline (phenMe2) a dimer is formed due to Te-(η6-C6) contacts. Te⋯N and Te⋯C interactions between Te(Cat36)2 and the diimines were found to be attractive and non-covalent (DFT and QTAIM). In accordance with the weakness of Te⋯N interactions, no ligand-to-ligand charge transfer (LLCT) bands were observed in the electronic spectra of the adducts.

UR - https://www.mendeley.com/catalogue/f9e67f22-98bf-3a3e-b3b7-35c8d7c08674/

U2 - 10.1039/d4nj02469a

DO - 10.1039/d4nj02469a

M3 - Article

VL - 48

SP - 15483

EP - 15492

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 35

ER -

ID: 122849716